Method of cleaning using partially fluorinated alkenes having a tertiary structure as solvent

ABSTRACT

Novel partially fluorinated alkenes having the Formula: ##STR1## wherein each R is the same or different and is selected from the group consisting of CF 3 , CHF 2 , CH 2  F, and CH 3  CF 2 , and R&#39; is an alkenyl or fluoroalkenyl group having 1 to 6 carbon atoms have utility as solvents in a variety of industrial cleaning applications including cold cleaning, dry cleaning, and defluxing of printed circuit boards.

This application is a division of application Ser. No. 622,877, filed Dec. 4, 1990 now U.S. Pat. No. 5,087,777.

FIELD OF THE INVENTION

This invention relates to novel partially fluorinated alkenes having a tertiary structure and 4 to 9 carbon atoms. These compounds are useful in a variety of vapor degreasing, cold cleaning, and solvent cleaning applications including defluxinq and dry cleaning.

BACKGROUND OF THE INVENTION

Cold cleaning is an application where numerous solvents are used. In most cold cleaning applications, the soiled part is either immersed in the fluid or wiped with rags or similar objects soaked in solvents and allowed to air dry.

In cold cleaning applications, the use of the aerosol packaging concept has long been found to be a convenient and cost effective means of dispensing solvents. Aerosol products utilize a propellant gas or mixture of propellant gases, preferably in a liquified gas rather than a compressed gas state, to generate sufficient pressure to expel the active ingredients, i.e. product concentrates such as solvents, from the container upon opening of the aerosol valve. The propellants may be in direct contact with the solvent, as in most conventional aerosol systems, or may be isolated from the solvent, as in barrier-type aerosol systems.

Vapor degreasing and solvent cleaning with fluorocarbon based solvents have found widespread use in industry for the degreasing and otherwise cleaning of solid surfaces, especially intricate parts and difficult to remove soils.

In its simplest form, vapor degreasing or solvent cleaning consists of exposing a room temperature object to be cleaned to the vapors of a boiling solvent. Vapors condensing on the object provide clean distilled solvent to wash away grease or other contamination. Final evaporation of solvent from the object leaves behind no residue as would be the case where the object is simply washed in liquid solvent

For soils which are difficult to remove, where elevated temperature is necessary to improve the cleaning action of the solvent, or for large volume assembly line operations where the cleaning of metal parts and assemblies must be done efficiently and quickly, the conventional operation of a vapor degreaser consists of immersing the part to be cleaned in a sump of boiling solvent which removes the bulk of the soil, thereafter immersing the part in a sump containing freshly distilled solvent near room temperature, and finally exposing the part to solvent vapors over the boiling sump which condense on the cleaned part. In addition, the part can also be sprayed with distilled solvent before final rinsing.

Vapor degreasers suitable in the above-described operations are well known in the art. For example, Sherliker et al. in U.S. Pat. No. 3,085,918 disclose such suitable vapor degreasers comprising a boiling sump, a clean sump, a water separator, and other ancillary equipment.

Chlorofluorocarbon solvents, such as trichlorotrifluoroethane, have attained widespread use in recent years as effective, nontoxic, and nonflammable agents useful in degreasing applications and other solvent cleaning applications. One isomer of trichlorotrifluoroethane is 1,1,2-trichloro-1,2,2-trifluoroethane (known in the art as CFC-113). CFC-113 has a boiling point of about 47° C. and has been found to have satisfactory solvent power for greases, oils, waxes and the like. It has therefore found widespread use for cleaning electric motors, compressors, heavy metal parts, delicate precision metal parts, printed circuit boards, gyroscopes, guidance systems, aerospace and missile hardware, aluminum parts and the like.

Another commonly used solvent is chloroform (known in the art as HCC-20) which has a boiling point of about 63° C. Perchloroethylene is a commonly used dry cleaning and vapor degreasing solvent which has a boiling point of about 121° C. These compounds are disadvantageous for use as solvents because they are toxic; also, chloroform causes liver damage when inhaled in excess.

Although chlorine is known to contribute to the solvency capability of a compound, fully halogenated chlorofluorocarbons and hydrochlorocarbons are suspected of causing environmental problems in connection with the earth's protective ozone layer. Thus, the art is seeking new compounds which do not contribute to environmental problems but yet provide the solvency properties of CFC-113. From an environmental standpoint, partially fluorinated alkenes are of interest because they are considered to be stratospherically safe substitutes for the currently used fully halogenated chlorofluorocarbons.

It is an object of this invention to provide novel partially fluorinated alkenes which are liquid at room temperature and which are useful as solvents for use in vapor degreasing, cold cleaning, and other solvent cleaning applications including defluxing applications and dry cleaning.

Another object of the invention is to provide novel environmentally acceptable solvents for use in the aforementioned applications.

Other objects and advantages of the invention will become apparent from the following description.

DETAILED DESCRIPTION OF THE INVENTION

We have found a novel class of alkenes which we believe have good solvency characteristics. The present novel compounds are of the Formula: ##STR2## wherein each R is the same or different and is selected from the group consisting of CF₃, CHF₂, CH₂ F, and CH₃ CF₂ --, and R' is an alkenyl or fluoroalkenyl group having 1 to 6 carbon atoms.

Because C in the Formula above has two alkyl groups and an alkenyl or fluoroalkenyl group thereon, these novel compounds have a tertiary structure. We believe that this tertiary structure provides good solvency power. When the present compounds are used as solvents, the compounds have good solvency power for polar contaminants such as polyols and amines and also for nonpolar contaminants including hydrocarbons such as mineral oil. We also believe that these novel compounds have boiling points which are comparable to those of currently used solvents.

Preferably, R' in the Formula above is selected from the group consisting of CF₂ ═CF--, CF₂ ═CH--, CF₂ ═CFCF₂ --, CF₂ ═CFCH₂ --, CF₂ ═CFCHF--, CF₂ ═CHCF₂ --, CF₂ ═CHCH₂ --, CF₂ ═CHCHF--, CF₃ CF═CF--, CF₃ CF═CH--, CF₃ CH═CF--, CF₃ CH═CH--, CHF═CF--, CHF═CH--, CHF═CFCF₂ --, CHF═CFCH₂ --, CHF═CFCHF--, CHF═CHCF₂ --, CHF═CHCH₂ --, CHF═CHCHF--, CHF₂ CF═CF--, CHF₂ CF═CH--, CHF₂ CH═CF--, CHF₂ CH═CH--, CH₂ ═CF--, CH₂ ═CH--, CH₂ ═CFCF₂ --, CH₂ ═CFCH₂ --, CH₂ ═CFCHF--, CH₂ ═CHCF₂ --, CH₂ ═CHCH₂ --, CH₂ ═CHCHF--, CH₂ FCF═CF--, CH₂ FCF═CH--, CH₂ FCH═CF--, and CH.sub. 2 FCH═CH--.

Also preferably, R' in the Formula above is selected from the group consisting of CH₃ CF═CF--, CH₃ CF═CH--, CH₃ CH═CF--, CH₃ CH═CH--, CF₂ ═CFCF₂ CF₂ --, CF₂ ═CFCF₂ CHF--, CF₂ ═CFCF₂ CH₂ --, CF₂ ═CFCHFCF₂ --, CF₂ ═CFCHFCHF--, CF₂ ═CFCHFCH₂ --, CF₂ ═CFCH₂ CF₂ --, CF₂ ═CFCH₂ CHF--, CF₂ ═CFCH₂ CH₂ --, CF₂ ═CHCF₂ CF₂ --, CF₂ ═CHCF₂ CHF--, CF₂ ═CHCF₂ CH₂ --, CF₂ ═CHCHFCF₂ --, CF₂ ═CHCHFCHF--, CF₂ ═CHCHFCH₂ --, CF₂ ═CHCH₂ CF₂ --, CF₂ ═CHCH₂ CHF--, CF₂ ═CHCH₂ CH₂ --, CHF═CFCF₂ CF₂ --, CHF═CFCF₂ CHF--, CHF═CFCF₂ CH₂ --, CHF═CFCHFCF₂ --, CHF═CFCHFCHF--, CHF═CFCHFCH₂ --, CHF═CFCH₂ CF₂ --, CHF═CFCH₂ CHF--, CHF═CFCH₂ CH₂ --, CHF═CHCF₂ CF₂ --, CHF═CHCF₂ CHF--, CHF═CHCF₂ CH₂ --, CHF═CHCHFCF₂ --, CHF═CHCHFCHF--, CHF═CHCHFCH₂ --, CHF═CHCH₂ CF₂ --, CHF═CHCH₂ CHF--, CHF═CHCH₂ CH₂ --, CH₂ ═CFCF₂ CF₂ --, CH₂ ═CFCF₂ CHF--, CH₂ ═CFCF₂ CH₂ --, CH₂ ═CFCHFCF₂ --, CH₂ ═CFCHFCHF--, CH₂ ═CFCHFCH₂ --, CH₂ ═CFCH₂ CF₂ --, CH₂ ═CFCH₂ CHF--, CH₂ ═CFCH₂ CH₂ --, CH₂ ═CHCF₂ CF₂ --, CH₂ ═CHCF₂ CHF--, CH₂ ═CHCF₂ CH₂ --, CH₂ ═CHCHFCF₂ --, CH₂ ═CHCHFCHF--, CH₂ ═CHCHFCH₂ --, CH₂ ═CHCH₂ CF₂ -- , CH₂ ═CHCH₂ CHF--, and CH₂ ═CHCH₂ CH₂ --.

Also preferably, R' in the Formula above is selected from the group consisting of CF₃ CF═CFCF₂ --, CF₃ CF═CFCHF--, CF₃ CF═CFCH₂ --, CHF₂ CF═CFCF₂ --, CHF₂ CF═CFCHF--, CHF₂ CF═CFCH₂ --, CH₂ FCF═CFCF₂ --, CH₂ FCF═CFCHF--, CH₂ FCF═CFCH₂ --, CH₃ CF═CFCF₂ --, CH₃ CF═CFCHF--, CH₃ CF═CFCH₂ --, CF₃ CF═CHCF₂ --, CF₃ CF═CHCHF--, CF₃ CF═CHCH₂ --, CHF₂ CF═CHCF₂ --, CHF₂ CF═CHCHF--, CHF₂ CF═CHCH₂ --, CH₂ FCF═CHCF₂ --, CH₂ FCF═CHCHF--, CH₂ FCF═CHCH₂ --, CH₃ CF═CHCF₂ --, CH₃ CF═CHCHF--, CH₃ CF═CHCH₂ --, CF₃ CH═CFCF₂ --, CF₃ CH═CFCHF--, CF₃ CH═CFCH₂ --, CHF₂ CH═CFCF₂ --, CHF₂ CH═CFCHF--, CHF.sub. 2 CH═CFCH₂ --, CH₂ FCH═CFCF₂ --, CH₂ FCH═CFCHF--, CH₂ FCH═CFCH₂ --, CH₃ CH═CFCF₂ --, CH₃ CH═CFCHF--, CH₃ CH═CFCH₂ --, CF₃ CH═CHCF₂ --, CF₃ CH═CHCHF--, CF₃ CH═CHCH₂ --, CHF₂ CH═CHCF₂ --, CHF₂ CH═CHCHF--, CHF₂ CH═CHCH₂ --, CH₂ FCH═CHCF₂ --, CH₂ FCH═CHCHF--, CH₂ FCH═CHCH₂ --, CH₃ CH═CHCF₂ --, CH₃ CH═CHCHF--, and CH₃ CH═CHCH₂ --.

Also preferably R' in the Formula above is selected from the group consisting of CF₃ CF₂ CF═CF--, CF₃ CHFCF═CF--, CF₃ CH₂ CF═CF--, CHF₂ CF₂ CF═CF--, CHF₂ CHFCF═CF--, CHF₂ CH₂ CF═CF--, CH₂ FF₂ CF═CF--, CH₂ FCHFCF═CF--, CH₂ FCH₂ CF═CF--, CH₃ CF₂ CF═CF--, CH₃ CHFCF═CF--, CH₃ CH₂ CF═CF--, CF₃ CF₂ CF═CH--, CF₃ CHFCF═CH--, CF₃ CH₂ CF═CH--, CHF₂ CF₂ CF═CH--, CHF₂ CHFCF═CH--, CHF₂ CH₂ CF═CH--, CH₂ FF₂ CF═CH--, CH₂ FCHFCF═CH--, CH₂ FCH₂ CF═CH--, CH₃ CF₂ CF═CH--, CH₃ CHFCF═CH--, CH₃ CH₂ CF═CH--, CF₃ CF₂ CH═CF--, CF₃ CHFCH═CF--, CF₃ CH₂ CH═CF--, CHF₂ CF₂ CH═CF--, CHF₂ CHFCH═CF--, CHF₂ CH₂ CH═CF--, CH₂ FF₂ CH═CF--, CH₂ FCHFCH═CF--, CH₂ FCH₂ CH═CF--, CH₃ CF₂ CH═CF--, CH₃ CHFCH═CF--, CH₃ CH₂ CH═CF--, CF₃ CF₂ CH═CH--, CF₃ CHFCH═CH--, CF₃ CH₂ CH═CH--, CHF₂ CF₂ CH═CH--, CHF₂ CHFCH═CH--, CHF₂ CH₂ CH═CH--, CH₂ FF₂ CH═CH--, CH₂ FCHFCH═CH--, CH₂ FCH₂ CH═CH--, CH₃ CF₂ CH═CH--, CH₃ CHFCH═CH--, and CH₃ CH₂ CH═CH--.

In the Formula above, when one R is CF₃, the other R is CHF₂, and R' is CF₂ ═CH--, the compound is 2-fluoromethyl-1,1,1,4,4-pentafluoro-3-butene. When one R is CF₃, the other R is CHF₂, and R' is CHF═CF--, the compound is 2-fluoromethyl-1,1,1,3,4-pentafluoro-3-butene. When one R is CF₃, the other R is CHF₂, and R' is CHF═CH--, the compound is 2-fluoromethyl-1,1,1,4-tetrafluoro-3-butene.

Also in the Formula above, when one R is CF₃, the other R is CHF₂, and R' is CH₂ ═CFCF₂ --, the compound is 4-difluoromethyl-2,3,3,5,5,5-hexafluoro-1-pentene. When one R is CF₃, the other R is CHF₂, and R' is CH₃ CF═CF--, the compound 4-difluoromethyl-2,3,5,5,5-pentafluoro-1-pentene. When one R is CF₃, the other R is CHF₂, and R' is CH₂ ═CHCF₂ --, the compound is 4-difluoromethyl-3,3,5,5,5-pentafluoro-1-pentene. When one R is CF₃, the other R is CHF₂, and R' is CH₃ CH═CF--, the compound is 4-difluoromethyl-3,5,5,5-tetrafluoro-1-pentene.

When one R is CF₃, the other R is CH₂ F, and R' is CH₂ ═CFCF₂ --, the compound is 4-fluoromethyl-2,3,3,5,5,5-hexafluoro-1-pentene. When one R is CF₃, the other R is CH₂ F, and R' is CH₃ CF═CF--, the compound is 4-fluoromethyl-2,3,5,5,5-pentafluoro-1-pentene. When one R is CF₃, the other R is CH₂ F, and R' is CH₂ ═CFCF₂ --, the compound is 4-fluoromethyl-3,3,5,5,5-pentafluoro-1-pentene. When one R is CF₃, the other R is CH₂ F, and R' is CH₃ CH═CF--, the compound is 4-fluoromethyl-3,5,5,5-tetrafluoro-1-pentene. When one R is CF₃, the other R is CH₃ CF₂ --, and R' is CH₂ ═CF--, the compound is 3-trifluoromethyl-2,4,4-trifluoro-1-pentene.

It is believed that the present novel compounds may be prepared by adapting known methods for preparing known alkenes coupled with the knowledge of one skilled in the art. For example, commercially available 3-chloropropionic acid may be fluorinated to form 1,1,1,3-tetrafluoropropane which may then be reacted with CHF₂ CF carbene to form 2-fluoromethyl-1,1,1,3,4,4-hexafluorobutane which may then be dehydrohalogenated to form 2-fluoromethyl-1,1,1,4,4-pentafluoro-3-butene.

As another example, commercially available 3-chloropropionic acid may be fluorinated to form 1,1,1,3-tetrafluoropropane which may then be reacted with CHF₂ CF carbene to form 2-fluoromethyl-1,1,1,3,4,4-hexafluorobutane which may then be dehydrohalogenated to form 2-fluoromethyl-1,1,1,3,4-pentafluoro-3-butene.

As another example, commercially available 3-chloropropionic acid may be fluorinated to form 1,1,1,3-tetrafluoropropane which may then be reacted with CHF₂ CF carbene to form 2-fluoromethyl-1,1,1,3,4,4-hexafluorobutane which may then be dehalogenated to form 2-fluoromethyl-1,1,1,4-tetrafluoro-3-butene.

As another example, 4-difluoromethyl-2,3,3,5,5,5-hexafluoro-1-pentene may be prepared by fluorinating commercially available 2,3-pentanedione to form 2,2,3,3-tetrafluoropentane which may then be dehydrogenated to form 3,3,4,4-tetrafluoro-1-pentene. CF₃ may then be added to the 3,3,4,4-tetrafluoro-1-pentene to form 2-trifluoromethyl-1,3,3,4,4-pentafluoropentane which may then be dehydrogenated to form 2-trifluoromethyl-1,3,3,4,4-pentafluoro-1-pentene. The 2-trifluoromethyl-1,3,3,4,4-pentafluoro-1-pentene may then be reacted with hydrogen fluoride to form 2-trifluoromethyl-1,1,3,3,4,4-hexafluoropentane which may then be dehydrohalogenated to form 4-difluoromethyl-2,3,3,5,5,5-hexafluoro-1-pentene.

As another example, 4-difluoromethyl-2,3,5,5,5-pentafluoro-1-pentene may be prepared by fluorinating commercially available 2,3-pentanedione to form 2,2,3,3-tetrafluoropentane which may then be dehydroqenated to form 3,3,4,4-tetrafluoro-1-pentene. CF₃ may then be added to the 3,3,4,4-tetrafluoro-1-pentene to form 2-trifluoromethyl-1,3,3,4,4-pentafluoropentane which may then be dehydrogenated to form 2-trifluoromethyl-1,3,3,4,4-pentafluoro-1-pentene. The 2-trifluoromethyl-1,3,3,4,4-pentafluoro-1-pentene may then be reacted with hydrogen fluoride to form 2-trifluoromethyl-1,1,3,3,4,4-hexafluoropentane which may then be dehalogenated to form 4-difluoromethyl-2,3,5,5,5-pentafluoro-1-pentene.

As another example, 4-difluoromethyl-3,3,5,5,5-pentafluoro-1-pentene may be prepared by fluorinating 3-pentanone to form 3,3-difluoropentane which may then be dehydrogenated to form 3,3-difluoro-1-pentene. CF₃ may then be reacted with the 3,3-difluoro-1-pentene to form 2-trifluoromethyl-1,3,3-trifluoropentane which may then be dehydrogenated to form 2-trifluoromethyl-1,3,3-trifluoro-1-pentene. The 2-trifluoromethyl-1,3,3-trifluoro-1-pentene may then be reacted with hydrogen fluoride to form 2-trifluoromethyl-1,1,3,3-tetrafluoropentane which may then be dehydrogenated to form 4-difluoromethyl-3,3,5,5,5-pentafluoro-1-pentene.

As another example, 4-difluoromethyl-3,5,5,5-tetrafluoro-1-pentene may be prepared by fluorinating 3-pentanone to form 3,3-difluoropentane which may then be dehydrogenated to form 3,3-difluoro-1-pentene. CF₃ may then be reacted with the 3,3-difluoro-1-pentene to form 2-trifluoromethyl-1,3,3-trifluoropentane which may then be dehydrogenated to form 2-trifluoromethyl-1,3,3-trifluoro-1-pentene. The 2-trifluoromethyl-1,3,3-trifluoro-1-pentene may then be reacted with hydrogen fluoride to form 2-trifluoromethyl-1,1,3,3-tetrafluoropentane which may then be dehydrohalogenated to form 4-difluoromethyl-3,5,5,5-tetrafluoro-1-pentene.

As another example, 4-fluoromethyl-2,3,3,5,5,5-hexafluoro-1-pentene may be prepared by fluorinating commercially available 2,3-pentanedione to form 2,2,3,3-tetrafluoropentane which may then be dehydrogenated to form 3,3,4,4-tetrafluoro-1-pentene. CF₃ may then be added to the 3,3,4,4-tetrafluoro-1-pentene to form 2-trifluoromethyl-1,3,3,4,4-pentafluoropentane which may then be dehydrohalogenated to form 4-fluoromethyl-2,3,3,5,5,5-hexafluoro-1-pentene.

As another example, 4-fluoromethyl-2,3,5,5,5-pentafluoro-1-pentene may be prepared by fluorinating commercially available 2,3-pentanedione to form 2,2,3,3-tetrafluoropentane which may then be dehydrogenated to form 3,3,4,4-tetrafluoro-1-pentene. CF₃ may then be added to the 3,3,4,4-tetrafluoro-1-pentene to form 2-trifluoromethyl-1,3,3,4,4-pentafluoropentane which may then be dehalogenated to form 4-fluoromethyl-2,3,5,5,5-pentafluoro-1-pentene.

As another example, 4-fluoromethyl-3,3,5,5,5-pentafluoro-1-pentene may be prepared by fluorinating 3-pentanone to form 3,3-difluoropentane which may then be dehydrogenated to form 3,3-difluoro-1-pentene. CF₃ may then be reacted with the 3,3-difluoro-1-pentene to form 2-trifluoromethyl-1,3,3-trifluoropentane which may then be dehydrogenated to form 4-fluoromethyl-3,3,5,5,5-pentafluoro-1-pentene.

As another example, 4-fluoromethyl-3,5,5,5-tetrafluoro-1-pentene may be prepared by fluorinating 3-pentanone to form 3,3-difluoropentane which may then be dehydrogenated to form 3,3-difluoro-1-pentene. CF₃ may then be reacted with the 3,3-difluoro-1-pentene to form 2-trifluoromethyl-1,3,3-trifluoropentane which may then be dehydrohalogenated to form 4-fluoromethyl-3,5,5,5-tetrafluoro-1-pentene.

As another example, commercially available 2,4-pentanedione may be fluorinated to form 2,2,4,4-tetrafluoropentane which may then be dehydrohalogenated to form 2,4,4-trifluoro-2-pentene. The 2,4,4-trifluoro-2-pentene may then be reacted with CF₃ to form 3-trifluoromethyl-2,2,4,4-tetrafluoropentane which may then be dehydrohalogenated to form 3-trifluoromethyl-2,4,4-trifluoro-1-pentene.

More preferably, each R in the formula above is CF₃. When R' is CF₃ CF═CH--, the compound is 4-trifluoromethyl-1,1,1,2,5,5,5-heptafluoro-2-pentene. When R' is CF₂ ═CFCHF--, the compound is 4-trifluoromethyl-1,1,2,3,5,5,5-heptafluoro-1-pentene.

As another example, commercially available hexafluoropropene may be oligomerized with commercially available trimethylamine in a dipolar aprotic solvent such as commercially available tetrahydrofuran to provide (CF₃)₂ C:CFCF₂ CF₃ as taught by W. Brunskill et al., "Anionic Oligomerisation of Hexafluoropropene: Fission of a Carbon-Carbon Bond by Fluoride Ion", Chemical Communications, 1444 (1970); the (CF₃)₂ C:CFCF₂ CF₃ may then be hydrogenated to form 2-trifluoromethyl-1,1,1,3,4,4,5,5,5-nonafluoropentane. The 2-trifluoromethyl-1,1,1,3,4,4,5,5,5-nonafluoropentane may then be dehalogenated to form 4-trifluoromethyl-1,1,1,2,5,5,5-heptafluoro-2-pentene.

As another example, commercially available hexafluoropropene may be oligomerized with commercially available trimethylamine in a dipolar aprotic solvent such as commercially available tetrahydrofuran to provide (CF₃)₂ C:CFCF₂ CF₃ as taught by W. Brunskill et al., "Anionic Oligomerisation of Hexafluoropropene Fission of a Carbon-Carbon Bond by Fluoride Ion", Chemical Communications, 1444 (1970); the (CF₃)₂ C:CFCF₂ CF₃ may then be hydrogenated to form 2-trifluoromethyl-1,1,1,3,4,4,5,5,5-nonafluoropentane. The 2-trifluoromethyl-1,1,1,3,4,4,5,5,5-nonafluoropentane may then be dehalogenated to form 4-trifluoromethyl-1,1,2,3,5,5,5-heptafluoro-1-pentene.

Most preferably, each R is CF₃ and R' is selected from the group consisting of CF₂ ═CF--, CF₂ ═CH--, CHF═CH--, CH₂ ═CF--, CF₂ ═CFCF₂ --, CF₃ CF═CF--, CH₂ ═CFCF₂ --, CH₃ CF═CF--, CH₂ ═CHCF₂ --, and CH₃ CH═CF--. The names of the preceding preferred hydrofluorocarbons are 3-trifluoromethyl-1,1,2,4,4,4-hexafluoro-1-butene; 3-trifluoromethyl-1,1,4,4,4-pentafluoro-1-butene; 3-trifluoromethyl-1,4,4,4-tetrafluoro-1-butene; 3-trifluoromethyl-2,4,4,4-tetrafluoro-1-butene; 4-trifluoromethyl-1,1,2,3,3,5,5,5-octafluoro-1-pentene; 4-trifluoromethyl-1,1,1,2,3,5,5,5-octafluoro-2-pentene; 4-trifluoromethyl-2,3,3,5,5,5-hexafluoro-1-pentene; 4-trifluoromethyl-2,3,5,5,5-pentafluoro-1-pentene; 4-trifluoromethyl-3,3,5,5,5-pentafluoro-1-pentene; and 4-trifluoromethyl-3,5,5,5-tetrafluoro-1-pentene.

As another example, 3-trifluoromethyl-1,1,2,4,4,4-hexafluoro-1-butene may be prepared by reacting commercially available 1,1-difluoroethylene according to the procedure of George L. Fleming et al., "Addition of Free Radicals to Unsaturated Systems. Part XX. The Direction of Radical Addition of Heptafluoro-2-iodopropane to Vinyl Fluoride, Trifluoroethylene, and Hexafluoropropene", J.C.S. Perkin I, 574 (1973) to form a product which may then be fluorinated to form 2-trifluoromethyl-1,1,1,2,3,4,4,4-octafluorobutane. The 2-trifluoromethyl-1,1,1,2,3,4,4,4-octafluorobutane may then be dehydrohalogenated and then hydrogenated to form 2-trifluoromethyl-1,1,1,3,4,4,4-heptafluorobutane. The 2-trifluoromethyl-1,1,1,3,4,4,4-heptafluorobutane may then be dehydrohalogenated to form 3-trifluoromethyl-1,1,2,4,4,4-hexafluoro-1-butene.

As another example, 3-trifluoromethyl-1,1,4,4,4-pentafluoro-1-butene may be prepared by reacting commercially available 1,1-difluoroethylene according to the procedure of George L. Fleming et al., supra, to form a product which may then be reacted with hydrogen fluoride to form 2-trifluoromethyl-1,1,1,2,4,4,4-hexafluorobutane which may then be dehydrohalogenated and then hydrogenated to form 2-trifluoromethyl-1,1,1,4,4,4-hexafluorobutane. The 2-trifluoromethyl-1,1,1,4,4,4-hexafluorobutane may then be dehydrohalogenated to form 3-trifluoromethyl-1,1,4,4,4-pentafluoro-1-butene.

As another example, 3-trifluoromethyl-1,4,4,4-tetrafluoro-1-butene may be prepared by reacting commercially available 1,1-difluoroethylene according to the procedure of George L. Fleming et al., supra, to form a product which may then be hydrogenated to form 2-trifluoromethyl-1,1,1,2,4,4-hexafluorobutane which may then be dehydrohalogenated and then hydrogenated to from 2-trifluoromethyl-1,1,1,4,4-pentafluorobutane. The 2-trifluoromethyl-1,1,1,4,4-pentafluorobutane may then be dehydrohalogenated to form 3-trifluoromethyl-1,4,4,4-tetrafluoro-1-butene.

As another example, 3-trifluoromethyl-2,4,4,4-tetrafluoro-1-butene may be prepared by fluorinating commercially available 2-butanone to form 2,2-difluorobutane which may then be dehydrogenated to form 3,3-difluoro-1-butene. CF₃ may then be added to the 3,3-difluoro-1-butene to form 2-trifluoromethyl-1,3,3-trifluorobutane which may then be dehydroqenated to form 2-trifluoromethyl-1,3,3-trifluoro-1-butene. The 2-trifluoromethyl-1,3,3-trifluoro-1-butene may then be reacted with hydrogen fluoride to form 2-difluoromethyl-1,1,1,3,3-pentafluorobutane which may then be dehydrogenated to form 2-trifluoromethyl-1,1,3,3-tetrafluoro-1-butene which may then be reacted with hydrogen fluoride to form 2-trifluoromethyl-1,1,1,3,3-pentafluorobutane. The 2-trifluoromethyl-1,1,1,3,3-pentafluorobutane may then be dehydrohalogenated to form 3-trifluoromethyl-2,4,4,4-tetrafluoro-1-butene.

As another example, commercially available hexafluoropropene may be oligomerized with commercially available trimethylamine in a dipolar aprotic solvent such as commercially available tetrahydrofuran to provide (CF₃)₂ C:CFCF₂ CF₃ which is then reacted with commercially available hydrogen fluoride to yield 2-trifluoromethyl-1,1,1,3,3,4,4,5,5,5-decafluoropentane as taught by W. Brunskill et al., "Anionic Oligomerisation of Hexafluoropropene: Fission of a Carbon-Carbon Bond by Fluoride Ion", Chemical Communications, 1444 (1970). The 2-trifluoromethyl-1,1,1,3,3,4,4,5,5,5-decafluoropentane may then be dehalogenated to form 4-trifluoromethyl-1,1,2,3,3,5,5,5-octafluoro-1-pentene.

As another example, commercially available hexafluoropropene may be oligomerized with commercially available trimethylamine in a dipolar aprotic solvent such as commercially available tetrahydrofuran to provide (CF₃)₂ C:CFCF₂ CF₃ which is then reacted with commercially available hydrogen fluoride to yield 2-trifluoromethyl-1,1,1,3,3,4,4,5,5,5-decafluoropentane as taught by W. Brunskill et al., "Anionic Oligomerisation of Hexafluoropropene: Fission of a Carbon-Carbon Bond by Fluoride Ion", Chemical Communications, 1444 (1970). The 2-trifluoromethyl-1,1,1,3,3,4,4,5,5,5-decafluoropentane may then be dehalogenated to form 4-trifluoromethyl-1,1,1,2,3,5,5,5-octafluoro-2-pentene.

As another example, 4-trifluoromethyl-2,3,3,5,5,5-hexafluoro-1-pentene may be prepared by fluorinating commercially available 2,3-pentanedione to form 2,2,3,3-tetrafluoropentane which may then be dehydrogenated to form 3,3,4,4-tetrafluoro-1-pentene. CF₃ may then be added to the 3,3,4,4-tetrafluoro-1-pentene to form 2-trifluoromethyl-1,3,3,4,4-pentafluoropentane which may then be dehydrogenated to form 2-trifluoromethyl-1,3,3,4,4-pentafluoro-1-pentene. The 2-trifluoromethyl-1,3,3,4,4-pentafluoro-1-pentene may then be reacted with hydrogen fluoride to form 2-trifluoromethyl-1,1,3,3,4,4-hexafluoropentane which may then be dehydrogenated to form 2-trifluoromethyl-1,1,3,3,4,4-hexafluoro-1-pentene which may then be reacted with hydrogen fluoride to form 2-trifluoromethyl-1,1,1,3,3,4,4-heptafluoropentane. The 2-trifluoromethyl-1,1,1,3,3,4,4-heptafluoropentane may then be dehydrohalogenated to form 4-trifluoromethyl-2,3,3,5,5,5-hexafluoro-1-pentene.

As another example, 4-trifluoromethyl-2,3,5,5,5-pentafluoro-1-pentene may be prepared by fluorinating commercially available 2,3-pentanedione to form 2,2,3,3-tetrafluoropentane which may then be dehydrogenated to form 3,3,4,4-tetrafluoro-1-pentene. CF₃ may then be added to the 3,3,4,4-tetrafluoro-1-pentene to form 2-trifluoromethyl-1,3,3,4,4-pentafluoropentane which may then be dehydrogenated to form 2-trifluoromethyl-1,3,3,4,4-pentafluoro-1-pentene. The 2-trifluoromethyl-1,3,3,4,4-pentafluoro-1-pentene may then be reacted with hydrogen fluoride to form 2-trifluoromethyl-1,1,3,3,4,4-hexafluoropentane which may then be dehydrogenated to form 2-trifluoromethyl-1,1,3,3,4,4-hexafluoro-1-pentene which may then be reacted with hydrogen fluoride to form 2-trifluoromethyl-1,1,1,3,3,4,4-heptafluoropentane. The 2-trifluoromethyl-1,1,1,3,3,4,4-heptafluoropentane may then be dehalogenated to form 4-trifluoromethyl-2,3,5,5,5-pentafluoro-1-pentene.

As another example, 4-trifluoromethyl-3,3,5,5,5-pentafluoro-1-pentene may be prepared by fluorinating 3-pentanone to form 3,3-difluoropentane which may then be dehydrogenated to form 3,3-difluoro-1-pentene. CF₃ may then be reacted with the 3,3-difluoro-1-pentene to form 2-trifluoromethyl-1,3,3-trifluoropentane which may then be dehydrogenated to form 2-trifluoromethyl-1,3,3-trifluoro-1-pentene. The 2-trifluoromethyl-1,3,3-trifluoro-1-pentene may then be reacted with hydrogen fluoride to form 2-trifluoromethyl-1,1,3,3-tetrafluoropentane which may then be dehydrogenated to form 2-trifluoromethyl-1,1,3,3-tetrafluoro-1-pentene which may then be reacted with hydrogen fluoride to form 2-trifluoromethyl-1,1,1,3,3-pentafluoropentane. The 2-trifluoromethyl-1,1,1,3,3-pentafluoropentane may then be dehydrogenated to form 4-trifluoromethyl-3,3,5,5,5-pentafluoro-1-pentene.

As another example, 4-trifluoromethyl-3,5,5,5-tetrafluoro-1-pentene may be prepared by fluorinating 3-pentanone to form 3,3-difluoropentane which may then be dehydrogenated to form 3,3-difluoro-1-pentene. CF₃ may then be reacted with the 3,3-difluoro-1-pentene to form 2-trifluoromethyl-1,3,3-trifluoropentane which may then be dehydrogenated to form 2-trifluoromethyl-1,3,3-trifluoro-1-pentene. The 2-trifluoromethyl-1,3,3-trifluoro-1-pentene may then be reacted with hydrogen fluoride to form 2-trifluoromethyl-1,1,3,3-tetrafluoropentane which may then be dehydrogenated to form 2-trifluoromethyl-1,1,3,3-tetrafluoro-1-pentene which may then be reacted with hydrogen fluoride to form 2-trifluoromethyl-1,1,1,3,3-pentafluoropentane. The 2-trifluoromethyl-1,1,1,3,3-pentafluoropentane may then be dehydrohalogenated to form 4-trifluoromethyl-3,5,5,5-tetrafluoro-1-pentene.

The present compounds are useful as solvents for use in vapor degreasing and other solvent cleaning applications including defluxing, cold cleaning, dry cleaning, dewatering, decontamination, spot cleaning, aerosol propelled rework, extraction, particle removal, and surfactant cleaning applications. These compounds are also useful as blowing agents, Rankine cycle and absorption refrigerants, power fluids, and especially as refrigerants for centrifugal refrigeration chillers.

The present invention also provides a method of cleaning a solid surface which comprises treating the surface with a compound having the Formula: ##STR3## wherein each R is the same or different and is selected from the group consisting of CF₃, CHF₂, CH₂ F, and CH₃ CF₂, and R' is an alkenyl or fluoroalkenyl group having 1 to 6 carbon atoms.

Preferably, R' in the Formula above is selected from the group consisting of CF₂ ═CF--, CF₂ ═CH--, CF₂ ═CFCF₂ --, CF₂ ═CFCH₂ --, CF₂ ═CFCHF--, CF₂ ═CHCF₂ --, CF₂ ═CHCH₂ --, CF₂ ═CHCHF--, CF₃ CF═CF--, CF₃ CF═CH--, CF₃ CH═CF--, CF₃ CH═CH--, CHF═CF--, CHF═CH--, CHF═CFCF₂ --, CHF═CFCH₂ --, CHF═CFCHF--, CHF═CHCF₂ --, CHF═CHCH₂ --, CHF═CHCHF--, CHF₂ CF═CF--, CHF₂ CF═CH--, CHF₂ CH═CF--, CHF₂ CH═CH--, CH₂ ═CF--, CH₂ ═CH--, CH₂ ═CFCF₂ --, CH₂ ═CFCH₂ --, CH₂ ═CFCHF--, CH₂ ═CHCF₂ --, CH₂ ═CHCH₂ --, CH₂ ═CHCHF--, CH₂ FCF═CF--, CH₂ FCF═CH--, CH₂ FCH═CF--, and CH₂ FCH═CH--.

Also preferably, R' in the Formula above is selected from the group consisting of CH₃ CF═CF--, CH₃ CF═CH--, CH₃ CH═CF--, CH₃ CH═CH--, CF₂ ═CFCF₂ CF₂ --, CF₂ ═CFCF₂ CHF--, CF₂ ═CFCF₂ CH₂ --, CF₂ ═CFCHFCF₂ --, CF₂ ═CFCHFCHF--, CF₂ ═CFCHFCH₂ --, CF₂ ═CFCH₂ CF₂ --, CF₂ ═CFCH₂ CHF--, CF₂ ═CFCH₂ CH₂ --, CF₂ ═CHCF₂ CF₂ --, CF₂ ═CHCF₂ CHF--, CF₂ ═CHCF₂ CH₂ --, CF₂ ═CHCHFCF₂ --, CF₂ ═CHCHFCHF--, CF₂ ═CHCHFCH₂ --, CF₂ ═CHCH₂ CF₂ --, CF₂ ═CHCH₂ CHF--, CF₂ ═CHCH₂ CH₂ --, CHF═CFCF₂ CF₂ --, CHF═CFCF₂ CHF--, CHF═CFCF₂ CH₂ --, CHF═CFCHFCF₂ --, CHF═CFCHFCHF-- , CHF═CFCHFCH₂ --, CHF═CFCH₂ CF₂ --, CHF═CFCH₂ CHF--, CHF═CFCH₂ CH₂ --, CHF═CHCF₂ CF₂ --, CHF═CHCF₂ CHF--, CHF═CHCF₂ CH₂ --, CHF═CHCHFCF₂ --, CHF═CHCHFCHF--, CHF═CHCHFCH₂ --, CHF═CHCH₂ CF₂ --, CHF═CHCH₂ CHF--, CHF═CHCH₂ CH₂ --, CH₂ ═CFCF₂ CF₂ --, CH₂ ═CFCF₂ CHF--, CH₂ ═CFCF₂ CH₂ --, CH₂ ═CFCHFCF₂ --, CH₂ ═CFCHFCHF--, CH₂ ═CFCHFCH₂ --, CH₂ ═CFCH₂ CF₂ --, CH₂ ═CFCH₂ CHF--, CH₂ ═CFCH₂ CH₂ --, CH₂ ═CHCF₂ CF₂ --, CH₂ ═CHCF₂ CHF--, CH₂ ═CHCF₂ CH₂ --, CH₂ ═CHCHFCF₂ --, CH₂ ═CHCHFCHF--, CH₂ ═CHCHFCH₂ --, CH₂ ═CHCH₂ CF₂ --, CH₂ ═CHCH₂ CHF--, and CH₂ ═CHCH₂ CH₂ --.

Also preferably, R' in the Formula above is selected from the group consisting of CF₃ CF═CFCF₂ --, CF₃ CF═CFCHF--, CF₃ CF═CFCH₂ --, CHF₂ CF═CFCF₂ --, CHF₂ CF═CFCHF--, CHF₂ CF═CFCH₂ --, CH₂ FCF═CFCF₂ --, CH₂ FCF═CFCHF--, CH₂ FCF═CFCH₂ --, CH₃ CF═CFCF₂ --, CH₃ CF═CFCHF--, CH₃ CF═CFCH₂ --, CF₃ CF═CHCF₂ --, CF₃ CF═CHCHF--, CF₃ CF═CHCH₂ --, CHF₂ CF═CHCF₂ --, CHF₂ CF═CHCHF--, CHF₂ CF═CHCH₂ --, CH₂ FCF═CHCF₂ --, CH₂ FCF═CHCHF--, CH₂ FCF═CHCH₂ --, CH₃ CF═CHCF₂ --, CH₃ CF═CHCHF--, CH₃ CF═CHCH₂ --, CF₃ CH═CFCF₂ --, CF₃ CH═CFCHF--, CF₃ CH═CFCH₂ --, CHF₂ CH═CFCF₂ --, CHF₂ CH═CFCHF--, CHF₂ CH═CFCH₂ --, CH₂ FCH═CFCF₂ --, CH₂ FCH═CFCHF--, CH₂ FCH═CFCH₂ --, CH₃ CH═CFCF₂ --, CH₃ CH═CFCHF--, CH₃ CH═CFCH₂ --, CF₃ CH═CHCF₂ --, CF₃ CH═CHCHF--, CF₃ CH═CHCH₂ --, CHF₂ CH═CHCF₂ --, CHF₂ CH═CHCHF--, CHF₂ CH═CHCH₂ --, CH₂ FCH═CHCF₂ --, CH₂ FCH═CHCHF--, CH₂ FCH═CHCH₂ --, CH₃ CH═CHCF₂ --, CH₃ CH═CHCHF--, and CH₃ CH═CHCH₂ --.

Also preferably, R' in the Formula above is selected from the group consisting of CF₃ CF₂ CF═CF--, CF₃ CHFCF═CF--, CF₃ CH₂ CF═CF--, CHF₂ CF₂ CF═CF--, CHF₂ CHFCF═CF--, CHF₂ CH₂ CF═CF--, CH₂ FF₂ CF═CF--, CH₂ FCHFCF═CF--, CH₂ FCH₂ CF═CF--, CH₃ CF₂ CF═CF--, CH₃ CHFCF═CF--, CH₃ CH₂ CF═CF--, CF₃ CF₂ CF═CH--, CF₃ CHFCF═CH--, CF₃ CH₂ CF═CH--, CHF₂ CF₂ CF═CH--, CHF₂ CHFCF═CH--, CHF₂ CH₂ CF═CH--, CH₂ FF₂ CF═CH--, CH₂ FCHFCF═CH--, CH₂ FCH₂ CF═CH--, CH₃ CF₂ CF═CH--, CH₃ CHFCF═CH--, CH₃ CH₂ CF═CH--, CF₃ CF₂ CH═CF--, CF₃ CHFCH═CF--, CF₃ CH₂ CH═CF--, CHF₂ CF₂ CH═CF--, CHF₂ CHFCH═CF--, CHF.sub. 2 CH₂ CH═CF--, CH₂ FF₂ CH═CF--, CH₂ FCHFCH═CF--, CH₂ FCH₂ CH═CF--, CH₃ CF₂ CH═CF--, CH₃ CHFCH═CF--, CH₃ CH₂ CH═CF--, CF₃ CF₂ CH═CH--, CF₃ CHFCH═CH--, CF₃ CH₂ CH═CH--, CHF₂ CF₂ CH═CH--, CHF₂ CHFCH═CH--, CHF₂ CH₂ CH═CH--, CH₂ FF₂ CH═CH--, CH₂ FCHFCH═CH--, CH₂ FCH₂ CH═CH--, CH₃ CF₂ CH═CH--, CH₃ CHFCH═CH--, and CH₃ CH₂ CH═CH--.

In the process embodiment of the invention, the compositions may be used to clean solid surfaces by treating the surfaces with the compounds in any manner well known to the art such as by dipping or spraying or use of conventional degreasing apparatus.

When the novel compounds are used to clean solid surfaces by spraying the surfaces with the compounds, preferably, the novel compounds are sprayed onto the surfaces by using a propellant. Preferably, the propellant is selected from the group consisting of hydrochlorofluorocarbon, hydrofluorocarbon, and mixtures thereof. Useful hydrochlorofluorocarbon propellants include dichlorofluoromethane (known in the art as HCFC-21), chlorodifluoromethane (known in the art as HCFC-22), 1,1-dichloro-2,2-difluoroethane (known in the art as HCFC-132a), 1-chloro-2,2,2-trifluoroethane (known in the art as HCFC-133), and 1-chloro-1,1-difluoroethane (known in the art as HCFC-142b); commercially available HCFC-21, HCFC-22, and HCFC-142b may be used in the present invention. Useful hydrofluorocarbon propellants include trifluoromethane (known in the art as HFC-23), 1,1,1,2-tetrafluoroethane (known in the art as HFC-134a), and 1,1-difluoroethane (known in the art as HFC-152a); commercially available HFC-23 and HFC-152a may be used in the present invention. Until HFC-134a becomes available in commercial quantities, HFC-134a may be made by a known method such as that disclosed by U.S. Pat. No. 4,851,595. Preferred propellants include chlorodifluoromethane and 1,1,1,2-tetrafluoroethane.

The present invention is more fully illustrated by the following non-limiting Examples.

EXAMPLES 1-960

For each example, the novel compound of the Formula above having the R and R' groups as indicated in Table I below is made.

                  TABLE I                                                          ______________________________________                                         Example    R            R'                                                     ______________________________________                                          1         CF.sub. 3, CHF.sub.2                                                                        CF.sub.2 ═CF--                                      2         CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CH--                                      3         CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CFCF.sub.2 --                             4         CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CFCH.sub.2 --                             5         CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CFCHF--                                   6         CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CHCF.sub.2 --                             7         CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CHCH.sub.2 --                             8         CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CHCHF--                                   9         CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CF═CF--                                    10        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CF═CH--                                    11        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CH═CF--                                    12        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CH═CH--                                    13        CF.sub.3, CHF.sub.2                                                                         CHF═CF--                                            14        CF.sub.3, CHF.sub.2                                                                         CHF═CH--                                            15        CF.sub.3, CHF.sub.2                                                                         CHF═CFCF.sub.2 --                                   16        CF.sub.3, CHF.sub.2                                                                         CHF═CFCH.sub.2 --                                   17        CF.sub.3, CHF.sub.2                                                                         CHF═CFCHF--                                         18        CF.sub.3, CHF.sub.2                                                                         CHF═CHCF.sub.2 --                                   19        CF.sub.3, CHF.sub.2                                                                         CHF═CHCH.sub.2 --                                   20        CF.sub.3, CHF.sub.2                                                                         CHF═CHCHF--                                         21        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CF═CF--                                   22        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CF═CH--                                   23        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CH═CF--                                   24        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CH═CH--                                   25        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CF--                                      26        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CH--                                      27        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CFCF.sub.2 --                             28        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CFCH.sub.2 --                             29        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CFCHF--                                   30        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CHCF.sub.2 --                             31        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CHCH.sub.2 --                             32        CF.sub.3 , CHF.sub.2                                                                        CH.sub.2 ═CHCHF--                                   33        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCF═CF--                                   34        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCF═CH--                                   35        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCH═CF--                                   36        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCH═CH--                                   37        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CF═CF--                                    38        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CF═CH--                                    39        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CH═CF--                                    40        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CH═CH--                                    41        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CFCF.sub.2 CF.sub.2 --                    42        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CFCF.sub.2 CHF--                          43        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CFCF.sub.2 CH.sub.2 --                    44        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CFCHFCF.sub.2 --                          45        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CFCHFCHF--                                46        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CFCHFCH.sub.2 --                          47        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═ CFCH.sub.2 CF.sub.2 --                   48        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CFCH.sub.2 CHF--                          49        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CFCH.sub.2 CH.sub.2 --                    50        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CHCF.sub.2 CF.sub.2 --                    51        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CHCF.sub.2 CHF--                          52        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CHCF.sub.2 CH.sub.2 --                    53        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CHCHFCF.sub.2 --                          54        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CHCHFCHF--                                55        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CHCHFCH.sub.2 --                          56        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CHCH.sub.2 CF.sub.2 --                    57        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CHCH.sub.2 CHF--                          58        CF.sub.3, CHF.sub.2                                                                         CF.sub.2 ═CHCH.sub.2 CH.sub.2 --                    59        CF.sub.3, CHF.sub.2                                                                         CHF═CFCF.sub.2 CF.sub.2 --                          60        CF.sub.3, CHF.sub.2                                                                         CHF═CFCF.sub.2 CHF--                                61        CF.sub.3, CHF.sub. 2                                                                        CHF═CFCF.sub.2 CH.sub.2 --                          62        CF.sub.3, CHF.sub.2                                                                         CHF═CFCHFCF.sub.2 --                                63        CF.sub.3, CHF.sub.2                                                                         CHF═CFCHFCHF--                                      64        CF.sub.3, CHF.sub.2                                                                         CHF═CFCHFCH.sub.2 --                                65        CF.sub.3, CHF.sub.2                                                                         CHF═CFCH.sub.2 CF.sub.2 --                          66        CF.sub.3, CHF.sub.2                                                                         CHF═CFCH.sub.2 CHF--                                67        CF.sub.3, CHF.sub.2                                                                         CHF═CFCH.sub.2 CH.sub.2 --                          68        CF.sub.3, CHF.sub.2                                                                         CHF═CHCF.sub.2 CF.sub.2 --                          69        CF.sub.3, CHF.sub.2                                                                         CHF═CHCF.sub.2 CHF--                                70        CF.sub.3, CHF.sub.2                                                                         CHF═CHCF.sub.2 CH.sub.2 --                          71        CF.sub.3, CHF.sub.2                                                                         CHF═CHCHFCF.sub.2 --                                72        CF.sub.3, CHF.sub.2                                                                         CHF═CHCHFCHF--                                      73        CF.sub.3, CHF.sub.2                                                                         CHF═CHCHFCH.sub.2 --                                74        CF.sub.3, CHF.sub.2                                                                         CHF═CHCH.sub.2 CF.sub.2 --                          75        CF.sub.3, CHF.sub.2                                                                         CHF═CHCH.sub.2 CHF--                                76        CF.sub.3, CHF.sub.2                                                                         CHF═CHCH.sub.2 CH.sub.2 --                          77        CF.sub.3 , CHF.sub.2                                                                        CH.sub.2 ═CFCF.sub.2 CF.sub.2 --                    78        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CFCF.sub.2 CHF--                          79        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CFCF.sub.2 CH.sub.2 --                    80        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CFCHFCF.sub.2 --                          81        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CFCHFCHF--                                82        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CFCHFCH.sub.2 --                          83        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CFCH.sub.2 CF.sub.2 --                    84        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CFCH.sub.2 CHF--                          85        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CFCH.sub.2 CH.sub.2 --                    86        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CHCF.sub.2 CF.sub.2 --                    87        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CHCF.sub.2 CHF--                          88        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CHCF.sub.2 CH.sub.2 --                    89        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CHCHFCF.sub.2 --                          90        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CHCHFCHF--                                 91       CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CHCHFCH.sub.2 --                          92        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CHCH.sub.2 CF.sub.2 --                    93        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CHCH.sub.2 CHF--                          94        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 ═CHCH.sub.2 CH.sub.2 --                    95        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CF═CFCF.sub.2 --                           96        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CF═CFCHF--                                 97        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CF═CFCF.sub.2 --                           98        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CF═CFCHF--                                 99        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CF═CFCH.sub.2 --                          100        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CF═CFCF.sub.2 --                         101        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CF═CFCHF--                               102        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CF═CFCH.sub.2 --                         103        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCF═CFCF.sub.2 --                         104        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCF═CFCHF--                               105        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCF═CFCH.sub.2 --                         106        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CF═CFCF.sub.2 --                          107        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CF═CFCHF--                                108        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CF═CFCH.sub.2 --                          109        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CF═CHCF.sub.2 --                          110        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CF═CHCHF--                                111        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CF═CHCH.sub.2 --                          112        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CF═CHCF.sub.2 --                         113        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CF═CHCHF--                               114        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CF═CHCH.sub.2 --                         115        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCF═CHCF.sub.2 --                         116        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCF═CHCHF--                               117        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCF═CHCH.sub.2 --                         118        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CF═CHCF.sub.2 --                          119        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CF═CHCHF--                                120        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CF═CHCH.sub.2 --                          121        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CH═CFCF.sub.2 --                          122        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CH═CFCHF--                                123        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CH═CFCH.sub.2 --                          124        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CH═CFCF.sub.2 --                         125        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CH═CFCHF--                               126        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CH═CFCH.sub.2 --                         127        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCH═CFCF.sub.2 --                         128        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCH═CFCHF--                               129        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCH═CFCH.sub.2 --                         130        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CH═CFCF.sub.2 --                          131        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CH═CFCHF--                                132        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CH═CFCH.sub.2 --                          133        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CH═CHCF.sub.2 --                          134        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CH═CHCHF--                                135        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CH═CHCH.sub.2 --                          136        CF.sub. 3, CHF.sub.2                                                                        CHF.sub.2 CH═CHCF.sub.2 --                         137        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CH═CHCHF--                               138        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CH═CHCH.sub.2 --                         139        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCH═CHCF.sub.2 --                         140        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCH═CHCHF--                               141        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCH═CHCH.sub.2 --                         142        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CH═CHCF.sub.2 --                          143        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CH═CHCHF--                                144        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CH═CHCH.sub.2 --                          145        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CF.sub.2 CF═CF--                          146        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CHFCF═CF--                                147        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CH.sub.2 CF═CF--                          148        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CF.sub.2 CF═CF--                         149        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CHFCF═CF--                               150        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CH.sub.2 CF═CF--                         151        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FF.sub.2 CF═CF--                          152        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCHFCF═CF--                               153        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCH.sub.2 CF═CF--                         154        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CF.sub.2 CF═CF--                          155        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CHFCF═CF--                                156        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CH.sub.2 CF═CF--                          157        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CF.sub.2 CF═CH--                          158        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CHFCF═CH--                                159        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CH.sub.2 CF═CH--                          160        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CF.sub.2 CF═CH--                         161        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CHFCF═CH--                               162        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CH.sub.2 CF═CH--                         163        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FF.sub.2 CF═CH--                          164        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCHFCF═CH--                               165        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCH.sub.2 CF═CH--                         166        CH.sub.3, CHF.sub.2                                                                         CH.sub.3 CF.sub.2 CF═CH--                          167        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CHFCF═CH--                                168        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CH.sub.2 CF═CH--                          169        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CF.sub.2 CH═CF--                          170        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CHFCH═CF--                                171        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CH.sub.2 CH═CF--                          172        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CF.sub.2 CH═CF--                         173        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CHFCH═CF--                               174        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CH.sub.2 CH═CF--                         175        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FF.sub.2 CH═CF--                          176        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCHFCH═CF--                               177        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCH.sub.2 CH═CF--                         178        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CF.sub.2 CH═CF--                          179        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CHFCH═CF--                                180        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CH.sub.2 CH═CF--                          181        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CF.sub.2 CH═CH--                          182        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CHFCH═CH--                                183        CF.sub.3, CHF.sub.2                                                                         CF.sub.3 CH.sub.2 CH═CH--                          184        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CF.sub.2 CH═CH--                         185        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CHFCH═CH--                               186        CF.sub.3, CHF.sub.2                                                                         CHF.sub.2 CH.sub.2 CH═CH--                         187        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FF.sub.2 CF═CH--                          188        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCHFCH═CH--                               189        CF.sub.3, CHF.sub.2                                                                         CH.sub.2 FCH.sub.2 CH═CH--                         190        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CF.sub.2 CH═CH--                          191        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CHFCH═CH--                                192        CF.sub.3, CHF.sub.2                                                                         CH.sub.3 CH.sub.2 CH═CH--                          193        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CF--                                     194        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CH--                                     195        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CFCF.sub.2 --                            196        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CFCH.sub.2 --                            197        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CFCHF--                                  198        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CHCF.sub.2 --                            199        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CHCH.sub.2 --                            200        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CHCHF--                                  201        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CF═CF--                                   202        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CF═CH--                                   203        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CH═CF--                                   204        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CH═CH--                                   205        CF.sub.3, CH.sub.2 F                                                                        CHF═CF--                                           206        CF.sub.3, CH.sub.2 F                                                                        CHF═CH--                                           207        CF.sub.3, CH.sub.2 F                                                                        CHF═CFCF.sub.2 --                                  208        CF.sub.3, CH.sub.2 F                                                                        CHF═CFCH.sub.2 --                                  209        CF.sub.3, CH.sub.2 F                                                                        CHF═CFCHF--                                        210        CF.sub.3, CH.sub.2 F                                                                        CHF═CHCF.sub.2 --                                  211        CF.sub.3, CH.sub.2 F                                                                        CHF═CHCH.sub.2 --                                  212        CF.sub.3, CH.sub.2 F                                                                        CHF═CHCHF--                                        213        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CF═CF--                                  214        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CF═CH--                                  215        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CH═CF--                                  216        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CH═CH--                                  217        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CF--                                     218        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CH--                                     219        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CFCF.sub.2 --                            220        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CFCH.sub.2 --                            221        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CFCHF--                                  222        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CHCF.sub.2 --                            223        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CHCH.sub.2 --                            224        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CHCHF--                                  225        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCF═CF--                                  226        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCF═CH--                                  227        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCH═CF--                                  228        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCH═CH--                                  229        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CF═CF--                                   230        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CF═CH--                                   231        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CH═CF--                                   232        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CH═CH--                                   233        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CFCF.sub.2 CF.sub.2 --                   234        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CFCF.sub.2 CHF--                         235        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CFCF.sub.2 CH.sub.2 --                   236        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CFCHFCF.sub.2 --                         237        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CFCHFCHF--                               238        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CFCHFCH.sub.2 --                         239        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CFCH.sub.2 CF.sub.2 --                   240        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CFCH.sub.2 CHF--                         241        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CFCH.sub.2 CH.sub.2 --                   242        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CHCF.sub.2 CF.sub.2 --                   243        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CHCF.sub.2 CHF--                         244        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CHCF.sub.2 CH.sub.2 --                   245        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CHCHFCF.sub.2 --                         246        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CHCHFCHF--                               247        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CHCHFCH.sub.2 --                         248        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CHCH.sub.2 CF.sub.2 --                   249        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CHCH.sub.2 CHF--                         250        CF.sub.3, CH.sub.2 F                                                                        CF.sub.2 ═CHCH.sub.2 CH.sub.2 --                   251        CF.sub.3, CH.sub.2 F                                                                        CHF═CFCF.sub.2 CF.sub.2 --                         252        CF.sub.3, CH.sub.2 F                                                                        CHF═CFCF.sub.2 CHF--                               253        CF.sub.3, CH.sub.2 F                                                                        CHF═CFCF.sub.2 CH.sub.2 --                         254        CF.sub.3, CH.sub.2 F                                                                        CHF═CFCHFCF.sub.2 --                               255        CF.sub.3, CH.sub.2 F                                                                        CHF═CFCHFCHF--                                     256        CF.sub.3, CH.sub.2 F                                                                        CHF═CFCHFCH.sub.2 --                               257        CF.sub.3, CH.sub.2 F                                                                        CHF═CFCH.sub.2 CF.sub.2 --                         258        CF.sub.3, CH.sub. 2 F                                                                       CHF═CFCH.sub.2 CHF--                               259        CF.sub.3, CH.sub.2 F                                                                        CHF═CFCH.sub.2 CH.sub.2                            260        CF.sub.3, CH.sub.2 F                                                                        CHF═CHCF.sub.2 CF.sub.2 --                         261        CF.sub.3, CH.sub.2 F                                                                        CHF═CHCF.sub.2 CHF--                               262        CF.sub.3, CH.sub.2 F                                                                        CHF═CHCF.sub.2 CH.sub.2 --                         263        CF.sub.3, CH.sub.2 F                                                                        CHF═CHCHFCF.sub.2 --                               264        CF.sub.3, CH.sub.2 F                                                                        CHF═CHCHFCHF--                                     265        CF.sub.3, CH.sub.2 F                                                                        CHF═CHCHFCH.sub.2 --                               266        CF.sub.3, CH.sub.2 F                                                                        CHF═CHCH.sub.2 CF.sub.2 --                         267        CF.sub.3, CH.sub.2 F                                                                        CHF═CHCH.sub.2 CHF--                               268        CF.sub.3, CH.sub.2 F                                                                        CHF═CHCH.sub.2 CH.sub.2 --                         269        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CFCF.sub.2 CF.sub.2 --                   270        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CFCF.sub.2 CHF--                         271        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CFCF.sub.2 CH.sub.2 --                   272        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CFCHFCF.sub.2 --                         273        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CFCHFCHF--                               274        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CFCHFCH.sub.2 --                         275        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CFCH.sub.2 CF.sub.2 --                   276        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CFCH.sub.2 CHF--                         277        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CFCH.sub.2 CH.sub.2 --                   278        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CHCF.sub.2 CF.sub.2 --                   279        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CHCF.sub.2 CHF--                         280        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CHCF.sub.2 CH.sub.2 --                   281        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CHCHFCF.sub.2 --                         282        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CHCHFCHF--                               283        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CHCHFCH.sub.2 --                         284        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CHCH.sub.2 CF.sub.2 --                   285        CF.sub.3, CH.sub.2 F                                                                        CH.sub. 2 ═CHCH.sub.2 CHF--                        286        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 ═CHCH.sub.2 CH.sub.2 --                   287        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CF═CFCF.sub.2 --                          288        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CF═CFCHF--                                289        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CF═CFCF.sub.2 --                          290        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CF═CFCHF--                                291        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CF═CFCH.sub.2 --                          292        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CF═CFCF.sub.2 --                         293        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CF═CFCHF--                               294        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CF═CFCH.sub.2 --                         295        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCF═CFCF.sub.2 --                         296        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCF═CFCHF--                               297        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCF═CFCH.sub.2 --                         298        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CF═CFCF.sub.2 --                          299        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CF═CFCHF--                                300        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CF═CFCH.sub.2 --                          301        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CF═CHCF.sub.2 --                          302        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CF═CHCHF--                                303        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CF═CHCH.sub.2 --                          304        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CF═CHCF.sub.2 --                         305        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CF═CHCHF--                               306        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CF═CHCH.sub.2 --                         307        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCF═CHCF.sub.2 --                         308        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCF═CHCHF--                               309        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCF═CHCH.sub.2 --                         310        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CF═CHCF.sub.2 --                          311        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CF═CHCHF--                                312        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CF═CHCH.sub.2 --                          313        CF.sub.3, CH.sub. 2 F                                                                       CF.sub.3 CH═CFCF.sub.2 --                          314        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CH═CFCHF--                                315        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CH═CFCH.sub.2 --                          316        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CH═CFCF.sub.2 --                         317        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CH═CFCHF--                               318        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CH═CFCH.sub.2 --                         319        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCH═CFCF.sub.2 --                         320        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCH═CFCHF--                               321        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCH═CFCH.sub.2 --                         322        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CH═CFCF.sub.2 --                          323        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CH═CFCHF--                                324        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CH═CFCH.sub.2 --                          325        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CH═CHCF.sub.2 --                          326        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CH═CHCHF--                                327        CF.sub.3, CH.sub. 2 F                                                                       CF.sub.3 CH═CHCH.sub.2 --                          328        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CH═CHCF.sub.2 --                         329        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CH═CHCHF--                               330        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CH═CHCH.sub.2 --                         331        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCH═CHCF.sub.2 --                         332        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCH═CHCHF--                               333        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCH═CHCH.sub.2 --                         334        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CH═CHCF.sub.2 --                          335        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CH═CHCHF--                                336        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CH═CHCH.sub.2 --                          337        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CF.sub.2 CF═CF--                          338        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CHFCF═CF--                                339        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CH.sub.2 CF═CF--                          340        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CF.sub.2 CF═CF--                         341        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CHFCF═ CF--                              342        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CH.sub.2 CF═CF--                         343        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FF.sub.2 CF═CF--                          344        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCHFCF═CF--                               345        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCH.sub.2 CF═CF--                         346        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CF.sub.2 CF═CF--                          347        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CHFCF═CF--                                348        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CF.sub.2 CF═CF--                          349        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CF.sub.2 CF═CF--                          350        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CHFCF═CH--                                351        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CH.sub.2 CF═CH--                          352        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CF.sub.2 CF═CH--                         353        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CHFCF═CH--                               354        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CH.sub.2 CF═CF--                         355        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FF.sub.2 CF═CH--                          356        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCHFCF═ CH--                              357        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCH.sub.2 CF═CH--                         358        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CF.sub.2 CF═CF--                          359        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CHFCF═CH--                                360        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CH.sub.2 CF═CH--                          361        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CF.sub.2 CH═CF--                          362        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CHFCH═CF--                                363        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CH.sub.2 CH═CF--                          364        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CF.sub.2 CH═CF--                         365        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CHFCH═CF--                               366        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CH.sub.2 CH═CF--                         367        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FF.sub.2 CH═CF--                          368        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCHFCH═CF--                               369        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCH.sub.2 CH═CF--                         370        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CF.sub.2 CH═CF--                          371        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CHFCH═ CF--                               372        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CH.sub.2 CH═CF--                          373        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CF.sub.2 CH═CH--                          374        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CHFCH═CH--                                375        CF.sub.3, CH.sub.2 F                                                                        CF.sub.3 CH.sub.2 CH═CH--                          376        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CF.sub.2 CH═CH--                         377        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CHFCH═CH--                               378        CF.sub.3, CH.sub.2 F                                                                        CHF.sub.2 CH.sub.2 CH═CH--                         379        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FF.sub.2 CH═CH--                          380        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCHFCH═CH--                               381        CF.sub.3, CH.sub.2 F                                                                        CH.sub.2 FCH.sub.2 CH═CH--                         382        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CF.sub.2 CH═CH--                          383        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CHFCH═CH--                                384        CF.sub.3, CH.sub.2 F                                                                        CH.sub.3 CH.sub.2 CH═CH--                          385        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CF--                                     386        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═ CH--                                    387        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CFCF.sub.2 --                            388        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CFCH.sub.2 --                            389        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CFCHF--                                  390        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CHCF.sub.2 --                            391        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CHCH.sub.2 --                            392        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CHCHF--                                  393        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CF═CF--                                   394        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CF═CH--                                   395        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CH═CF--                                   396        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CH═CH--                                   397        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CF--                                           398        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CH--                                           399        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CFCF.sub.2 --                                  400        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CFCH.sub.2 --                                  401        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CCHF═CFCHF--                                       402        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CHCF.sub.2 --                                  403        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CHCH.sub.2 --                                  404        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CHCHF--                                        405        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CF═CF--                                  406        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CF═CH--                                  407        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CH═CF--                                  408        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CH═CH--                                  409        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CF--                                     410        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CH--                                     411        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CFCF.sub.2 --                            412        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CFCH.sub.2 --                            413        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CFCHF--                                  414        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CHCF.sub.2 --                            415        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CHCH.sub.2 --                            416        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CHCHF--                                  417        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCF═CF--                                  418        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCF═CH--                                  419        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCH═CF--                                  420        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCH═CH--                                  421        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CF═CF--                                   422        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CF═CH--                                   423        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CH═CF--                                   424        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CH═CH--                                   425        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CFCF.sub.2 CF.sub.2 --                   426        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CFCF.sub.2 CHF--                         427        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CFCF.sub.2 CH.sub.2 --                   428        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CFCHFCF.sub.2 --                         429        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CFCHFCHF--                               430        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CFCHFCH.sub.2 --                         431        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CFCH.sub.2 CF.sub.2 --                   432        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CFCH.sub.2 CHF--                         433        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CFCH.sub.2 CH.sub.2 --                   434        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CHCF.sub.2 CF.sub.2 --                   435        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CHCF.sub.2 CHF--                         436        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CHCF.sub.2 CH.sub.2 --                   437        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CHCHFCF.sub.2 --                         438        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CHCHFCHF--                               439        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CHCHFCH.sub.2 --                         440        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CHCH.sub.2 CF.sub.2 --                   441        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CHCH.sub.2 CHF--                         442        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.2 ═CHCH.sub.2 CH.sub.2 --                   443        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CFCF.sub.2 CF.sub.2 --                         444        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CFCF.sub.2 CHF--                               445        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CFCF.sub.2 CH.sub.2 --                         446        CF.sub.3, CH.sub.3 CH.sub.2                                                                 CHF═CFCHFCF.sub.2 --                               447        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CFCHFCHF--                                     448        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CFCHFCH.sub.2 --                               449        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CFCH.sub.2 CF.sub.2 --                         450        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CFCH.sub.2 CHF--                               451        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CFCH.sub.2 CH.sub.2 --                         452        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CHCF.sub.2 CF.sub.2 --                         453        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CHCF.sub.2 CHF--                               454        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CHCF.sub.2 CH.sub.2 --                         455        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CHCHFCF.sub.2 --                               456        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CHCHFCHF--                                     457        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CHCHFCH.sub.2 --                               458        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CHCH.sub.2 CF.sub.2 --                         459        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CHCH.sub.2 CHF--                               460        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF═CHCH.sub.2 CH.sub.2 --                         461        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CFCF.sub.2 CF.sub.2 --                   462        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CFCF.sub.2 CHF--                         463        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CFCF.sub.2 CH.sub.2 --                   464        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CFCHFCF.sub.2 --                         465        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CFCHFCHF--                               466        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CFCHFCH.sub.2 --                         467        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CFCH.sub.2 CF.sub.2 --                   468        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CFCH.sub.2 CHF--                         469        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CFCH.sub.2 CH.sub.2 --                   470        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CHCF.sub.2 CF.sub.2 --                   471        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CHCF.sub.2 CHF--                         472        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CHCF.sub.2 CH.sub.2 --                   473        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CHCHFCF.sub.2 --                         474        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CHCHFCHF--                               475        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CHCHFCH.sub.2 --                         476        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CHCH.sub.2 CF.sub.2 --                   477        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CHCH.sub.2 CHF--                         478        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 ═CHCH.sub.2 CH.sub.2 --                   479        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CF═CFCF.sub.2 --                          480        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CF═CFCHF--                                481        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CF═ CFCF.sub.2 --                         482        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CF═CFCHF--                                483        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CF═CFCH.sub.2 --                          484        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CF═CFCF.sub.2 --                         485        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CF═CFCHF--                               486        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CF═CFCH.sub.2 --                         487        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCF═CFCF.sub.2 --                         488        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCF═CFCHF--                               489        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCF═CFCH.sub.2 --                         490        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CF═CFCF.sub.2 --                          491        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CF═CFCHF--                                492        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CF═CFCH.sub.2 --                          493        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CF═CHCF.sub.2 --                          494        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CF═ CHCHF--                               495        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CF═CHCH.sub.2 --                          496        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CF═CHCF.sub.2 --                         497        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CF═CHCHF--                               498        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CF═CHCH.sub.2 --                         499        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCF═CHCF.sub.2 --                         500        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCF═CHCHF--                               501        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCF═CHCH.sub.2 --                         502        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CF═CHCF.sub.2 --                          503        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CF═CHCHF--                                504        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CF═CHCH.sub.2 --                          505        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CH═CFCF.sub.2 --                          506        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CH═CFCHF--                                507        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CH═CFCH.sub.2 --                          508        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CH═CFCF.sub.2 --                         509        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CH═CFCHF--                               510        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CH═CFCH.sub.2 --                         511        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCH═CFCF.sub.2 --                         512        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCH═CFCHF--                               513        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCH═CFCH.sub.2 --                         514        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CH═CFCF.sub.2 --                          515        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CH═CFCHF--                                516        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CH═CFCH.sub.2 --                          517        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CH═CHCF.sub.2 --                          518        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CH═CHCHF--                                519        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CH═CHCH.sub.2 --                          520        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CH═CHCF.sub.2 --                         521        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CH═CHCHF--                               522        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CH═CHCH.sub.2 --                         523        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCH═CHCF.sub.2 --                         524        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCH═CHCHF--                               525        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCH═CHCH.sub.2 --                         526        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CH═CHCF.sub.2 --                          527        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CH═CHCHF--                                528        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CH═CHCH.sub.2 --                          529        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CF.sub.2 CF═CF--                          530        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CHFCF═CF--                                531        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CH.sub.2 CF═CF--                          532        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CF.sub.2 CF═CF--                         533        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CHFCF═CF--                               534        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CH.sub.2 CF═CF--                         535        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FF.sub.2 CF═CF--                          536        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCHFCF═CF--                               537        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCH.sub.2 CF═CF--                         538        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CF.sub.2 CF═CF--                          539        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CHFCF═CF--                                540        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CH.sub.2 CF═CF--                          541        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CF.sub.2 CF═CH--                          542        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CHFCF═CH--                                543        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CH.sub.2 CF═CH--                          544        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CF.sub.2 CF═CH--                         545        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CHFCF═CH--                               546        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CH.sub.2 CF═CH--                         547        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FF.sub.2 CF═CH--                          548        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCHFCF═CH--                               549        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCH.sub.2 CF═CH--                         550        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CF.sub.2 CF═CH--                          551        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CHFCF═CH--                                552        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CH.sub.2 CF═CH--                          553        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CF.sub.2 CH═CF--                          554        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CHFCH═CF--                                555        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CH.sub.2 CH═CF--                          556        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CF.sub.2 CH═CF--                         557        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CHFCH═CF--                               558        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CH.sub.2 CH═CH--                         559        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FF.sub.2 CH═CF--                          560        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCHFCH═CF--                               561        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCH.sub.2 CH═CF--                         562        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CF.sub.2 CH═CF--                          563        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CHFCH═CF--                                564        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CH.sub.2 CH═CF--                          565        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CF.sub.2 CH═CH--                          566        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CHFCH═CH--                                567        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CF.sub.3 CH.sub.2 CH═CH--                          568        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CF.sub.2 CH═CH--                         569        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CHFCH═CH--                               570        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CHF.sub.2 CH.sub.2 CH═CH--                         571        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FF.sub.2 CH═CH--                          572        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.2 FCHFCH═CH--                               573        CF.sub.3, CH.sub.3 CH.sub.2                                                                 CH.sub.2 FCH.sub.2 CH═CH--                         574        CF.sub.3, CH.sub.3 CH.sub.2                                                                 CH.sub.3 CF.sub.2 CH═CH--                          575        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CHFCH═CH--                                576        CF.sub.3, CH.sub.3 CF.sub.2                                                                 CH.sub.3 CH.sub.2 CH═CH--                          577        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CF--                                     578        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CH--                                     579        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CFCF.sub.2 --                            580        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CFCH.sub.2 --                            581        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CFCHF--                                  582        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CHCF.sub.2 --                            583        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CHCH.sub.2 --                            584        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CHCHF--                                  585        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CF═CF--                                   586        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CF═CH--                                   587        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CH═CF--                                   588        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CH═CH--                                   589        CHF.sub.2, CH.sub.2 F                                                                       CHF═CF--                                           590        CHF.sub.2, CH.sub.2 F                                                                       CHF═CH--                                           591        CHF.sub.2, CH.sub.2 F                                                                       CHF═CFCF.sub.2 --                                  592        CHF.sub.2, CH.sub.2 F                                                                       CHF═CFCH.sub.2 --                                  593        CHF.sub.2, CH.sub.2 F                                                                       CHF═CFCHF--                                        594        CHF.sub.2, CH.sub.2 F                                                                       CHF═CHCF.sub.2 --                                  595        CHF.sub.2, CH.sub.2 F                                                                       CHF═CHCH.sub.2 --                                  596        CHF.sub.2, CH.sub.2 F                                                                       CHF═CHCHF--                                        597        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CF═CF--                                  598        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CF═CH--                                  599        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CH═CF--                                  600        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CH═CH--                                  601        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CF--                                     602        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CH--                                     603        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CFCF.sub.2 --                            604        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CFCH.sub.2 --                            605        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CFCHF--                                  606        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CHCF.sub.2 --                            607        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CHCH.sub.2 --                            608        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CHCHF--                                  609        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCF═CF--                                  610        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCF═CH--                                  611        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCH═CF--                                  612        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCH═CH--                                  613        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CF═CF--                                   614        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CF═CH--                                   615        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CH═CF--                                   616        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CH═CH--                                   617        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CFCF.sub.2 CF.sub.2 --                   618        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CFCF.sub.2 CHF--                         619        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CFCF.sub.2 CH.sub.2 --                   620        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CFCHFCF.sub.2 --                         621        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CFCHFCHF--                               622        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CFCHFCH.sub.2 --                         623        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CFCH.sub.2 CF.sub.2 --                   624        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CFCH.sub.2 CHF--                         625        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CFCH.sub.2 CH.sub.2 --                   626        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CHCF.sub.2 CF.sub.2 --                   627        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CHCF.sub.2 CHF--                         628        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CHCF.sub.2 CH.sub.2 --                   629        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CHCHFCF.sub.2 --                         630        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CHCHFCHF--                               631        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CHCHFCH.sub.2 --                         632        CHF.sub.2 , CH.sub.2 F                                                                      CF.sub.2 ═CHCH.sub.2 CF.sub.2 --                   633        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CHCH.sub.2 CHF--                         634        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.2 ═CHCH.sub.2 CH.sub.2 --                   635        CHF.sub.2, CH.sub.2 F                                                                       CHF═CFCF.sub.2 CF.sub.2 --                         636        CHF.sub.2, CH.sub.2 F                                                                       CHF═CFCF.sub.2 CHF--                               637        CHF.sub.2, CH.sub.2 F                                                                       CHF═CFCF.sub.2 CH.sub.2 --                         638        CHF.sub.2, CH.sub.2 F                                                                       CHF═CFCHFCF.sub.2 --                               639        CHF.sub.2, CH.sub.2 F                                                                       CHF═CFCHFCHF--                                     640        CHF.sub.2, CH.sub.2 F                                                                       CHF═CFCHFCH.sub.2 --                               641        CHF.sub.2, CH.sub.2 F                                                                       CHF═CFCH.sub.2 CF.sub.2 --                         642        CHF.sub.2, CH.sub.2 F                                                                       CHF═CFCH.sub.2 CHF--                               643        CHF.sub.2, CH.sub.2 F                                                                       CHF═CFCH.sub.2 CH.sub.2 --                         644        CHF.sub.2, CH.sub.2 F                                                                       CHF═CHCF.sub.2 CF.sub.2 --                         645        CHF.sub.2, CH.sub.2 F                                                                       CHF═CHCF.sub.2 CHF--                               646        CHF.sub.2, CH.sub.2 F                                                                       CHF═CHCF.sub.2 CH.sub.2 --                         647        CHF.sub.2 , CH.sub.2 F                                                                      CHF═CHCHFCF.sub.2 --                               648        CHF.sub.2, CH.sub.2 F                                                                       CHF═CHCHFCHF--                                     649        CHF.sub.2, CH.sub.2 F                                                                       CHF═CHCHFCH.sub.2 --                               650        CHF.sub.2, CH.sub.2 F                                                                       CHF═CHCH.sub.2 CF.sub.2 --                         651        CHF.sub.2, CH.sub.2 F                                                                       CHF═CHCH.sub.2 CHF--                               652        CHF.sub.2, CH.sub.2 F                                                                       CHF═CHCH.sub.2 CH.sub.2 --                         653        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CFCF.sub.2 CF.sub.2 --                   654        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CFCF.sub.2 CHF--                         655        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CFCF.sub.2 CH.sub.2 --                   656        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CFCHFCF.sub.2 --                         657        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CFCHFCHF--                               658        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CFCHFCH.sub.2 --                         659        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CFCH.sub.2 CF.sub.2 --                   660        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CFCH.sub.2 CHF--                         661        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CFCH.sub.2 CH.sub. 2 --                  662        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CHCF.sub.2 CF.sub.2 --                   663        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CHCF.sub.2 CHF--                         664        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CHCF.sub.2 CH.sub.2 --                   665        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CHCHFCF.sub.2 --                         666        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CHCHFCHF--                               667        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CHCHFCH.sub.2 --                         668        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CHCH.sub.2 CF.sub.2 --                   669        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CHCH.sub.2 CHF--                         670        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 ═CHCH.sub.2 CH.sub.2 --                   671        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CF═CFCF.sub.2 --                          672        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CF═CFCHF--                                673        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CF═CFCF.sub.2 --                          674        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CF═CFCHF--                                675        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CF═CFCH.sub.2 --                          676        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CF═CFCF.sub.2 --                         677        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CF═CFCHF--                               678        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CF═CFCH.sub.2 --                         679        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCF═CFCF.sub.2 --                         680        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCF═CFCHF--                               681        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCF═CFCH.sub.2 --                         682        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CF═CFCF.sub.2 --                          683        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CF═CFCHF--                                684        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CF═CFCH.sub.2 --                          685        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CF═CHCF.sub.2 --                          686        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CF═CHCHF--                                687        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CF═CHCH.sub.2 --                          688        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CF═CHCF.sub.2 --                         689        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CF═CHCHF--                               690        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CF═CHCH.sub.2 --                         691        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCF═CHCF.sub.2 --                         692        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCF═CHCHF--                               693        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCF═CHCH.sub.2 --                         694        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CF═CHCF.sub.2 --                          695        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CF═CHCHF--                                696        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CF═CHCH.sub.2 --                          697        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CH═CFCF.sub.2 --                          698        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CH═CFCHF--                                699        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CH═CFCH.sub.2 --                          700        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CH═CFCF.sub.2 --                         701        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CH═CFCHF--                               702        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CH═CFCH.sub.2 --                         703        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCH═CFCF.sub.2 --                         704        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCH═CFCHF--                               705        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCH═CFCH.sub.2 --                         706        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CH═CFCF.sub.2 --                          707        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CH═CFCHF--                                708        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CH═CFCH.sub.2 --                          709        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CH═CHCF.sub.2 --                          710        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CH═CHCHF--                                711        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CH═CHCH.sub.2 --                          712        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CH═CHCF.sub.2 --                         713        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CH═CHCHF--                               714        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CH═CHCH.sub.2 --                         715        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCH═CHCF.sub.2 --                         716        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCH═CHCHF--                               717        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCH═CHCH.sub.2 --                         718        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CH═CHCF.sub.2 --                          719        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CH═CHCHF--                                720        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CH═CHCH.sub.2 --                          721        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CF.sub.2 CF═CF--                          722        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CHFCF═CF--                                723        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CH.sub.2 CF═CF--                          724        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CF.sub.2 CF═CF--                         725        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CHFCF═CF--                               726        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CH.sub.2 CF═CF--                         727        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FF.sub.2 CF═CF--                          728        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCHFCF═CF--                               729        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCH.sub.2 CF═CF--                         730        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CF.sub.2 CF═CF--                          731        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CHFCF═CF--                                732        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CH.sub.2 CF═CF--                          733        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CF.sub.2 CF═CH--                          734        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CHFCF═CH--                                735        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CH.sub.2 CF═CH--                          736        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CF.sub.2 CF═CH--                         737        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CHFCF═CH--                               738        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CH.sub.2 CF═CH--                         739        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FF.sub.2 CF═CH--                          740        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCHFCF═CH--                               741        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCH.sub.2 CF═CH--                         742        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CF.sub.2 CF═CH--                          743        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CHFCF═CH--                                744        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CH.sub.2 CF═CH--                          745        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CF.sub.2 CH═CF--                          746        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CHFCH═CF--                                747        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CH.sub.2 CH═CF--                          748        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CF.sub.2 CH═CF--                         749        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CHFCH═CF--                               750        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CH.sub.2 CH═CF--                         751        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FF.sub.2 CH═CF--                          752        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCHFCH═CF--                               753        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCH.sub.2 CH═CF--                         754        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CF.sub.2 CH═CF--                          755        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CHFCH═CF--                                756        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CH.sub.2 CH═CF--                          757        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CF.sub.2 CH═CH--                          758        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CHFCH═CH--                                759        CHF.sub.2, CH.sub.2 F                                                                       CF.sub.3 CH.sub.2 CH═CH--                          760        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CF.sub.2 CH═CH--                         761        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CHFCH═CH--                               762        CHF.sub.2, CH.sub.2 F                                                                       CHF.sub.2 CH.sub.2 CH═CH--                         763        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FF.sub.2 CH═CH--                          764        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCHFCH═CH--                               765        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.2 FCH.sub.2 CH═CH--                         766        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CF.sub.2 CH═CH--                          767        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CHFCH═CH--                                768        CHF.sub.2, CH.sub.2 F                                                                       CH.sub.3 CH.sub.2 CH═CH--                          769        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CF--                                     770        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CH--                                     771        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CFCF.sub.2 --                            772        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CFCH.sub.2 --                            773        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CFCHF--                                  774        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CHCF.sub.2 --                            775        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CHCH.sub.2 --                            776        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CHCHF--                                  777        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CF═CF--                                   778        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CF═CH--                                   779        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CH═CF--                                   780        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CH═CH--                                   781        CF.sub.3, CF.sub.3                                                                          CHF═ CF--                                          782        CF.sub.3, CF.sub.3                                                                          CHF═CH--                                           783        CF.sub.3, CF.sub.3                                                                          CHF═CFCF.sub.2 --                                  784        CF.sub.3, CF.sub.3                                                                          CHF═CFCH.sub.2 --                                  785        CF.sub.3, CF.sub.3                                                                          CHF═CFCHF--                                        786        CF.sub.3, CF.sub.3                                                                          CHF═CHCF.sub.2 --                                  787        CF.sub.3, CF.sub.3                                                                          CHF═CHCH.sub.2 --                                  788        CF.sub.3, CF.sub.3                                                                          CHF═CHCHF--                                        789        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CF═CF--                                  790        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CF═CH--                                  791        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CH═CF--                                  792        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CH═CH--                                  793        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CF--                                     794        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CH--                                     795        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CFCF.sub.2 --                            796        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CFCH.sub.2 --                            797        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CFCHF--                                  798        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CHCF.sub.2 --                            799        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CHCH.sub.2 --                            800        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CHCHF--                                  801        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCF═CF--                                  802        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCF═CH--                                  803        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCH═CF--                                  804        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCH═CH--                                  805        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CF═CF--                                   806        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CF═CH--                                   807        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CH═CF--                                   808        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CH═CH--                                   809        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CFCF.sub.2 CF.sub.2 --                   810        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CFCF.sub.2 CHF--                         811        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CFCF.sub.2 CH.sub.2 --                   812        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CFCHFCF.sub.2 --                         813        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CFCHFCHF--                               814        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CFCHFCH.sub.2 --                         815        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CFCH.sub.2 CF.sub.2 --                   816        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CFCH.sub.2 CHF--                         817        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CFCH.sub.2 CH.sub.2 --                   818        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CHCF.sub.2 CF.sub.2 --                   819        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CHCF.sub.2 CHF--                         820        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CHCF.sub.2 CH.sub.2 --                   821        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CHCHFCF.sub.2 --                         822        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CHCHFCHF--                               823        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CHCHFCH.sub.2 --                         824        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CHCH.sub.2 CF.sub.2 --                   825        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CHCH.sub.2 CHF--                         826        CF.sub.3, CF.sub.3                                                                          CF.sub.2 ═CHCH.sub.2 CH.sub.2 --                   827        CF.sub.3, CF.sub.3                                                                          CHF═CFCF.sub. 2 CF.sub.2 --                        828        CF.sub.3, CF.sub.3                                                                          CHF═CFCF.sub.2 CHF--                               829        CF.sub.3, CF.sub.3                                                                          CHF═CFCF.sub.2 CH.sub.2 --                         830        CF.sub.3, CF.sub.3                                                                          CHF═CFCHFCF.sub.2 --                               831        CF.sub.3, CF.sub.3                                                                          CHF═CFCHFCHF--                                     832        CF.sub.3, CF.sub.3                                                                          CHF═CFCHFCH.sub.2 --                               833        CF.sub.3, CF.sub.3                                                                          CHF═CFCH.sub.2 CF.sub.2 --                         834        CF.sub.3, CF.sub.3                                                                          CHF═CFCH.sub.2 CHF--                               835        CF.sub.3, CF.sub.3                                                                          CHF═CFCH.sub.2 CH.sub.2 --                         836        CF.sub.3, CF.sub.3                                                                          CHF═CHCF.sub.2 CF.sub.2 --                         837        CF.sub.3, CF.sub.3                                                                          CHF═CHCF.sub.2 CHF--                               838        CF.sub.3, CF.sub.3                                                                          CHF═CHCF.sub.2 CH.sub.2 --                         839        CF.sub.3, CF.sub.3                                                                          CHF═CHCHFCF.sub.2 --                               840        CF.sub.3, CF.sub.3                                                                          CHF═CHCHFCHF--                                     841        CF.sub.3, CF.sub.3                                                                          CHF═CHCHFCH.sub.2 --                               842        CF.sub.3, CF.sub.3                                                                          CHF═CHCH.sub.2 CF.sub.2 --                         843        CF.sub.3, CF.sub.3                                                                          CHF═CHCH.sub.2 CHF--                               844        CF.sub.3, CF.sub.3                                                                          CHF═CHCH.sub.2 CH.sub.2 --                         845        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CFCF.sub.2 CF.sub.2 --                   846        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CFCF.sub.2 CHF--                         847        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CFCF.sub.2 CH.sub.2 --                   848        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CFCHFCF.sub.2 --                         849        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CFCHFCHF--                               850        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CFCHFCH.sub.2 --                         851        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CFCH.sub.2 CF.sub.2 --                   852        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CFCH.sub.2 CHF--                         853        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CFCH.sub.2 CH.sub.2 --                   854        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CHCF.sub.2 CF.sub.2 --                   855        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CHCF.sub.2 CHF--                         856        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CHCF.sub.2 CH.sub.2 --                   857        CF.sub.3, CF.sub. 3                                                                         CH.sub.2 ═CHCHFCF.sub.2 --                         858        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CHCHFCHF--                               859        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CHCHFCH.sub.2 --                         860        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CHCH.sub.2 CF.sub.2 --                   861        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CHCH.sub.2 CHF--                         862        CF.sub.3, CF.sub.3                                                                          CH.sub.2 ═CHCH.sub.2 CH.sub.2 --                   863        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CF═CFCF.sub.2 --                          864        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CF═CFCHF--                                865        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CF═CFCF.sub.2 --                          866        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CF═CFCHF--                                867        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CF═CFCH.sub.2 --                          868        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CF═CFCF.sub.2 --                         869        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CF═CFCHF--                               870        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CF═CFCH.sub.2 --                         871        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCF═CFCF.sub.2 --                         872        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCF═CFCHF--                               873        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCF═CFCH.sub.2 --                         874        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CF═CFCF.sub.2 --                          875        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CF═CFCHF--                                876        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CF═CFCH.sub.2 --                          877        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CF═CHCF.sub.2 --                          878        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CF═CHCHF--                                879        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CF═CHCH.sub.2 --                          880        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CF═CHCF.sub.2 --                         881        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CF═CHCHF--                               882        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CF═CHCH.sub.2 --                         883        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCF═CHCF.sub.2 --                         884        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCF═CHCHF--                               885        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCF═CHCH.sub.2 --                         886        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CF═CHCF.sub.2 --                          887        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CF═CHCHF--                                888        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CF═CHCH.sub.2 --                          889        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CH═CFCF.sub.2 --                          890        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CH═CFCHF--                                891        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CH═CFCH.sub.2 --                          892        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CH═CFCF.sub.2 --                         893        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CH═CFCHF--                               894        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CH═CFCH.sub.2 --                         895        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCH═CFCF.sub.2 --                         896        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCH═CFCHF--                               897        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCH═CFCH.sub.2 --                         898        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CH═CFCF.sub.2 --                          899        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CH═CFCHF--                                900        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CH═CFCH.sub.2 --                          901        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CH═CHCF.sub.2 --                          902        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CH═CHCHF--                                903        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CH═CHCH.sub.2 --                          904        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CH═CHCF.sub.2 --                         905        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CH═CHCHF--                               906        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CH═CHCH.sub.2 --                         907        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCH═CHCF.sub.2 --                         908        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCH═CHCHF--                               909        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCH═CHCH.sub.2 --                         910        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CH═CHCF.sub.2 --                          911        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CH═CHCHF--                                912        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CH═CHCH.sub.2 --                          913        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CF.sub.2 CF═CF--                          914        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CHFCF═CF--                                915        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CH.sub.2 CF═CF--                          916        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CF.sub.2 CF═CF--                         917        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CHFCF═CF--                               918        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CH.sub.2 CF═CF--                         919        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FF.sub.2 CF═CF--                          920        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCHFCF═CF--                               921        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCH.sub.2 CF═CF--                         922        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CF.sub.2 CF═CF--                          923        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CHFCF═CF--                                924        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CH.sub.2 CF═CF--                          925        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CF.sub.2 CF═CH--                          926        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CHFCF═CH--                                927        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CH.sub.2 CF═CH--                          928        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CF.sub.2 CF═CH--                         929        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CHFCF═CH--                               930        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CH.sub.2 CF═CH--                         931        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FF.sub.2 CF═CH--                          932        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCHFCF═CH--                               933        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCH.sub.2 CF═CH--                         934        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CF.sub.2 CF═CH--                          935        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CHFCF═CH--                                936        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CH.sub.2 CF═CH--                          937        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CF.sub.2 CH═CF--                          938        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CHFCH═CF--                                939        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CH.sub.2 CH═CF--                          940        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CF.sub.2 CH═CF--                         941        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CHFCH═CF--                               942        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CH.sub.2 CH═CF--                         943        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FF.sub.2 CH═CF--                          944        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCHFCH═CF--                               945        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCH.sub.2 CH═CF--                         946        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CF.sub.2 CH═CF--                          947        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CHFCH═CF--                                948        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CH.sub.2 CH═CF--                          949        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CF.sub.2 CH═CH--                          950        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CHFCH═CH--                                951        CF.sub.3, CF.sub.3                                                                          CF.sub.3 CH.sub.2 CH═CH--                          952        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CF.sub.2 CH═CH--                         953        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CHFCH═CH--                               954        CF.sub.3, CF.sub.3                                                                          CHF.sub.2 CH.sub.2 CH═CH--                         955        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FF.sub.2 CH═CH--                          956        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCHFCH═CH--                               957        CF.sub.3, CF.sub.3                                                                          CH.sub.2 FCH.sub.2 CH═CH--                         958        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CF.sub.2 CH═CH--                          959        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CHFCH═CH--                                960        CF.sub.3, CF.sub.3                                                                          CH.sub.3 CH.sub.2 CH═CH--                          ______________________________________                                    

EXAMPLES 961-1,152

The novel compounds of these Examples have the same R' groups as Examples 1-192 but instead, the two R groups are CHF₂, and CH₃ CF₂.

EXAMPLES 1,153-1,344

The novel compounds of these Examples have the same R' groups as Examples 1-192 but instead, the two R groups are CH₂ F and CH₃ CF₂.

EXAMPLES 1,345-1,536

The novel compounds of these Examples have the same R' groups as Examples 1-192 but instead, the two R groups are CHF₂ and CHF₂.

EXAMPLES 1,537-1,728

The novel compounds of these Examples have the same R' groups as Examples 1-192 but instead, the two R groups are CH₂ F and CH₂ F.

EXAMPLES 1,729-1,920

The novel compounds of these Examples have the same R' groups as Examples 1-192 but instead, the two R groups are CH₃ CF₂ and CH₃ CF₂.

EXAMPLES 1,921-3,840

Metal coupons are soiled with various types of oil. The soiled metal coupons are immersed in the novel solvents of Table I above for a period of 15 seconds to 2 minutes, removed, and allowed to air dry. Upon visual inspection, the soil appears to be substantially removed.

EXAMPLES 3,841-5,760

Metal coupons are soiled with various types of oil. The soiled metal coupons are wiped with the novel solvents of Table I above and allowed to air dry. Upon visual inspection, the soil appears to be substantially removed.

Having described the invention in detail and by reference to preferred embodiments thereof, it will be apparent that modifications and variations are possible without departing from the scope of the invention defined in the appended claims. 

What is claimed is:
 1. A method of cleaning a solid surface having contaminants thereon which comprises the steps of:(a) contacting said surface with a compound having the formula ##STR4## wherein each R is the same or different and is selected from the group consisting of CF₃, CHF₂, CH₂ F, and CH₃ CF₂, and R' is an alkenyl or fluoroalkenyl group having 2 to 6 carbon atoms and (b) substantially removing said contaminants and said compound from said surface.
 2. The method of claim 1 wherein said R' is selected from the group consisting of CF₂ ═CF--, CF₂ ═CH--, CF₂ ═CFCF₂ --, CF₂ ═CFCH₂ --, CF₂ ═CFCHF--, CF₂ ═CHCF₂ --, CF₂ ═CHCH₂ --, CF₂ ═CHCHF--, CF₃ CF═CF--, CF₃ CF═CH--, CF₃ CH═CF--, CF₃ CH═CH--, CHF═CF--, CHF═CH--, CHF═CFCF₂ --, CHF═CFCH₂ --, CHF═CFCHF--, CHF═CHCF₂ --, CHF═CHCH₂ --, CHF═CHCHF--, CHF₂ CF═CF--, CHF₂ CF═CH--, CHF₂ CH═CF--, CHF₂ CH═CH--, CH₂ ═CF--, CH₂ ═CH--, CH₂ ═CFCF₂ --, CH₂ ═CFCH₂ --, CH₂ ═CFCHF--, CH₂ ═CHCF₂ --, CH₂ ═CHCH₂ --, CH₂ ═CHCHF--, CH₂ FCF═CF--, CH₂ FCF═CH--, CH₂ FCH═ CF--, and CH₂ FCH═CH--CF₃.
 3. The method of claim 1 wherein said R' is selected from the group consisting of CH₃ CF═CF--, CH₃ CF═CH--, CH₃ CH═CF--, CH₃ CH═CH--, CF₂ ═CFCF₂ CF₂ --, CF₂ ═CFCF₂ CHF--, CF₂ ═CFCF₂ CH₂ --, CF₂ ═CFCHFCF₂ --, CF₂ ═CFCHFCHF--, CF₂ ═CFCHFCH₂ --, CF₂ ═CFCH₂ CF₂ --, CF₂ ═CFCH₂ CHF--, CF₂ ═CFCH₂ CH₂ --, CF₂ ═CHCF₂ CF₂ --, CF₂ ═CHCF₂ CHF--, CF₂ ═CHCF₂ CH₂ --, CF₂ ═CHCHFCF₂ --, CF₂ ═CHCHFCHF--, CF₂ ═CHCHFCH₂ --, CF₂ ═CHCH₂ CF₂ --, CF₂ ═CHCH₂ CHF--, CF₂ ═CHCH₂ CH₂ --, CHF═CFCF₂ CF₂ --, CHF═CFCF₂ CHF--, CHF═CFCF₂ CH₂ --, CHF═CFCHFCF₂ -- , CHF═CFCHFCHF--, CHF═CFCHFCH₂ --, CHF═CFCH₂ CF₂ --, CHF═CFCH₂ CHF--, CHF═CFCH₂ CH₂ --, CHF═CHCF₂ CF₂ --, CHF═CHCF₂ CHF--, CHF═CHCF₂ CH₂ --, CHF═CHCHFCF₂ --, CHF═CHCHFCHF--, CHF═CHCHFCH₂ --, CHF═CHCH₂ CF₂ --, CHF═CHCH₂ CHF--, CHF═CHCH₂ CH₂ --, CH₂ ═CFCF₂ CF₂ --, CH₂ ═CFCF₂ CHF--, CH₂ ═CFCF₂ CH₂ --, CH₂ ═CFCHFCF₂ --, CH₂ ═CFCHFCHF--, CH₂ ═CFCHFCH₂ --, CH₂ ═CFCH₂ CF₂ --, CH₂ ═CFCH₂ CHF--, CH₂ ═CFCH₂ CH₂ --, CH₂ ═CHCF₂ CF₂ --, CH₂ ═CHCF₂ CHF--, CH₂ ═CHCF₂ CH₂ --, CH₂ ═CHCHFCF₂ --, CH₂ ═CHCHFCHF--, CH₂ ═CHCHFCH₂ --, CH₂ ═CHCH₂ CF₂ -- , CH₂ ═CHCH₂ CHF--, and CH₂ ═CHCH₂ CH₂ --.
 4. The method of claim 1 wherein said R' is selected from the group consisting of CF₃ CF═CFCF₂ --, CF₃ CF═CFCHF--, CF₃ CF═CFCH₂ --, CHF₂ CF═CFCF₂ --, CHF₂ CF═CFCHF--, CHF₂ CF═CFCH₂ --, CH₂ FCF═CFCF₂ --, CH₂ FCF═CFCHF--, CH₂ FCF═CFCH₂ --, CH₃ CF═CFCF₂ --, CH₃ CF═CFCHF--, CH₃ CF═CFCH₂ --, CF₃ CF═CHCF₂ --, CF₃ CF═CHCHF--, CF₃ CF═CHCH₂ --, CHF₂ CF═CHCF₂ --, CHF₂ CF═CHCHF--, CHF₂ CF═CHCH₂ --, CH₂ FCF═CHCF₂ --, CH₂ FCF═CHCHF--, CH₂ FCF═CHCH₂ --, CH₃ CF═CHCF₂ --, CH₃ CF═CHCHF--, CH₃ CF═CHCH₂ --, CF₃ CH═CFCF₂ --, CF₃ CH═CFCHF--, CF₃ CH═CFCH₂ --, CHF₂ CH═CFCF₂ --, CHF₂ CH═ CFCHF--, CHF₂ CH═CFCH₂ --, CH₂ FCH═CFCF₂ --, CH₂ FCH═CFCHF--, CH₂ FCH═CFCH₂ --, CH₃ CH═CFCF₂ --, CH₃ CH═CFCHF--, CH₃ CH═CFCH₂ --, CF₃ CH═CHCF₂ --, CF₃ CH═CHCHF--, CF₃ CH═CHCH₂ --, CHF₂ CH═CHCF₂ --, CHF₂ CH═CHCHF--, CHF₂ CH═CHCH₂ --, CH₂ FCH═CHCF₂ --, CH₂ FCH═CHCHF--, CH₂ FCH═CHCH₂ --, CH₃ CH═CHCF₂ --, CH₃ CH═CHCHF--, and CH₃ CH═CHCH₂ --.
 5. The method of claim 1 wherein said R' is selected from the group consisting of CF₃ CF₂ CF═CF--, CF₃ CHFCF═CF--, CF₃ CH₂ CF═CF--, CHF₂ CF₂ CF═CF--, CHF₂ CHFCF═CF--, CHF₂ CH₂ CF═CF--, CH₂ FF₂ CF═CF--, CH₂ FCHFCF═CF--, CH₂ FCH₂ CF═CF--, CH₃ CF₂ CF═CF--, CH₃ CHFCF═CF--, CH₃ CH₂ CF═CF--, CF₃ CF₂ CF═CH--, CF₃ CHFCF═CH--, CF₃ CH₂ CF═CH--, CHF₂ CF₂ CF═CH--, CHF₂ CHFCF═CH--, CHF₂ CH₂ CF═CH--, CH₂ FF₂ CF═CH--, CH₂ FCHFCF═CH--, CH₂ FCH₂ CF═CH--, CH₃ CF₂ CF═CH--, CH₃ CHFCF═CH--, CH₃ CH₂ CF═CH--, CF₃ CF₂ CH═CF--, CF₃ CHFCH═CF--, CF₃ CH₂ CH═CF--, CHF₂ CF₂ CH═CF--, CHF₂ CHFCH═ CF--, CHF₂ CH₂ CH═CF--, CH₂ FF₂ CH═CF--, CH₂ FCHFCH═CF--, CH₂ FCH₂ CH═CF--, CH₃ CF₂ CH═CF--, CH₃ CHFCH═CF--, CH₃ CH₂ CH═CF--, CF₃ CF₂ CH═CH--, CF₃ CHFCH═CH--, CF₃ CH₂ CH═CH--, CHF₂ CF₂ CH═CH--, CHF₂ CHFCH═CH--, CHF₂ CH₂ CH═CH--, CH₂ FF₂ CH═CH--, CH₂ FCHFCH═CH--, CH₂ FCH₂ CH═CH--, CH₃ CF₂ CH═CH--, CH₃ CHFCH═CH--, and CH₃ CH₂ CH═CH--.
 6. The method of claim 2 wherein each of said R is the same.
 7. The method of claim 3 wherein each of said R is the same.
 8. The method of claim 4 wherein each of said R is the same.
 9. The method of claim 5 wherein each of said R is the same.
 10. The method of claim 2 wherein each of said R is CF₃.
 11. The method of claim 3 wherein each of said R is CF₃.
 12. The method of claim 4 wherein each of said R is CF₃.
 13. The method of claim 5 wherein each of said R is CF₃.
 14. The method of claim 1 wherein said compound is selected from the group consisting of 3-trifluoromethyl-1,1,2,4,4,4-hexafluoro-1-butene; 3-trifluoromethyl-1,1,4,4,4-pentafluoro-1-butene; 3-trifluoromethyl-1,4,4,4-tetrafluoro-1-butene; 3-trifluoromethyl-2,4,4,4-tetrafluoro-1-butene; 4-trifluoromethyl-1,1,2,3,3,5,5,5-octafluoro-1-pentene; 4-trifluoromethyl-1,1,1,2,3,5,5,5-octafluoro-2-pentene; 4-trifluoromethyl-2,3,3,5,5,5-hexafluoro-1-pentene; 4-trifluoromethyl-2,3,5,5,5-pentafluoro-1-pentene; 4-trifluoromethyl-3,3,5,5,5-pentafluoro-1-pentene; and 4-trifluoromethyl-3,5,5,5-tetrafluoro-1-pentene. 